We solve the problem of scattering and binding of two spin-1/2 fermions on a one-dimensional superlattice with a period of twice the lattice spacing analytically. We find the exact bound states and the scattering states, consisting of a generalized Bethe ansatz augmented with an extra scattering product due to "asymptotic" degeneracy. If a Bloch band is doubly occupied, the extra wave can be a bound state in the continuum corresponding to a single-particle interband transition. In all other cases, it corresponds to a quasi-momentum changing, frustrated collision.