Existence of two phases in one-dimensional classical fluids

Andrews, Frank C.; Benson, Jesse

doi:10.1016/0031-9163(66)91028-6

Search citation statements

Order By: Relevance

Paper Sections

Select...

Model Thermodynamic Properties1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1966

2007

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 6 publications

(1 citation statement)

References 3 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A d , t isobar such as those in Figure is shown schematically as the solid curve in Figure . The dashed curve shows that this one-dimensional system is “trying” to undergo a liquid−vapor phase transition, which it fails to do because of the low dimensionality, but at low and high temperatures, it imitates realistically a liquid and its equilibrium vapor . At extremely low temperatures, not visible in Figure but shown in Figure , the liquid density rapidly rises from d = 0.8 to d = 1, where the liquid is then frozen into its close-packed structure.…”

Section: Model Thermodynamic Propertiesmentioning

confidence: 98%

Effect of Solutes on the Structure and Energetics of a Model Solvent

Gregorio

Widom

2007

J. Phys. Chem. C

View full text Add to dashboard Cite

The effect of solutes on the energetics of the solvent and the propagation of structural effects through the solvent are studied in a model one-dimensional liquid solution. The molecular origins of the difference between inserting a solute molecule into the solvent at fixed volume and at fixed pressure are illuminated. The relation between the potential of mean force between solutes at infinite dilution and the correlation function in the pure solvent is illustrated in the model.

show abstract

Section: Model Thermodynamic Propertiesmentioning

confidence: 98%