Evidence for the existence of a superheavy nucleus with atomic mass number A=292 and abundance (1-10)x10 -12 relative to 232 Th has been found in a study of natural Th using inductively coupled plasma-sector field mass spectrometry. The measured mass matches the predictions 1,2 for the mass of an isotope with atomic number Z=122 or a nearby element. Its estimated half-life of t 1/2 ≥10 8 y suggests that a long-lived isomeric state exists in this isotope. The possibility that it might belong to a new class of long-lived high spin super-and hyperdeformed isomeric states is discussed.
3-6The question "how heavy can a nucleus be" is a fundamental problem in nuclear physics. The mass M A of an atom is equal to:where M H and M n are the masses of the hydrogen atom and the neutron, respectively, and BE is the binding energy of the nucleus. The binding energy per nucleon (BE/u) of stable nuclei has a broad maximum around A ≈ 60, with a value of 8.7 MeV/u, which falls monotonically to about 7.6 MeV/u at Th and U. 19 The predicted BE/u values for the superactinide nuclei are around 6.9 MeV/u. 1,2,20,21 Therefore, masses of superactinide isotopes are higher than, and resolvable from, the masses of all molecules with the same mass number, except for multihydrogen-containing molecules. This is seen in Fig. 1 In principle, natural minerals like monazite, which is the usual source material for Th, would be the most promising materials to study. However, background was the main obstacle when looking for isotopes with relative abundance of (1-10)x10 -11 in natural materials.
10Therefore, purified natural Th was used in our measurements.In the present work, we performed accurate mass measurements for masses 287 to 294 in Th solutions. Evidence was obtained for the existence of an isotope with a mass that matches the predictions for atomic mass number 292 and Z around 122. Here we describe this observation.The experimental procedure was similar to that described earlier. 10 Inductively coupled plasma-sector field mass spectrometry (ICP-SFMS) was used for the experiments. The ICP-SFMS is an Element2 (Finnigan, Thermo-Electron, Bremen, Germany). In this instrument, a solution of the material to be studied is introduced into a high temperature (6000-8000 K) plasma source. At these temperatures, predominantly atomic species are present. Molecular ions are produced after the source, mainly by interaction with oxygen and hydrogen ions from the solution. The predefined medium resolution mode, m/∆m = 4000 (10% valley definition), was used throughout to separate atomic ions from molecules with the same mass number. The sensitivity-enhanced set-up of the instrument was similar to that described in Ref. During the first session, masses from 287 to 294 were analysed using the Th solutions with an integration time of 1 s channel -1 , and these measurements were made three to five times each. In one spectrum, two events were observed with a solution produced by CustomerGrade (from LGC Promochem AB, Borås, Sweden) at a mass that fits the predic...