Exfoliation and functionalization of α-zirconium phosphate in one pot for waterborne epoxy coatings with enhanced anticorrosion performance

Huang, Haowei; Li, Menglan; Tian, Yun; Xie, Yuhui; Sheng, Xinxin; Jiang, Xiang; Zhang, Xinya

doi:10.1016/j.porgcoat.2019.105390

Cited by 43 publications

(25 citation statements)

References 57 publications

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“…ZrP has been successfully exfoliated and its nanosheets used for different applications [ 6 , 21 , 43 , 44 , 45 , 46 , 47 , 48 , 49 , 50 ]. The most widely used strategy for ZrP exfoliation consists of the intercalation of small amine cations that can easily displace the protons from the phosphate groups in an acid-base reaction and enter the interlayer space [ 51 ].…”

Section: Synthesis and Preparation Of Zrp Nanomaterialsmentioning

confidence: 99%

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Preparation of Zirconium Phosphate Nanomaterials and Their Applications as Inorganic Supports for the Oxygen Evolution Reaction

Ramos-Garcés

Colón

2020

Nanomaterials

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Zirconium phosphate (ZrP) nanomaterials have been studied extensively ever since the preparation of the first crystalline form was reported in 1964. ZrP and its derivatives, because of their versatility, have found applications in several fields. Herein, we provide an overview of some advancements made in the preparation of ZrP nanomaterials, including exfoliation and morphology control of the nanoparticles. We also provide an overview of the advancements made with ZrP as an inorganic support for the electrocatalysis of the oxygen evolution reaction (OER). Emphasis is made on how the preparation of the ZrP electrocatalysts affects the activity of the OER.

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Section: Synthesis and Preparation Of Zrp Nanomaterialsmentioning

confidence: 99%

“…Recently, an ZrP exfoliation procedure using Tris-(hydroxymethyl)-aminomethane (Tris) was reported [ 48 ]. For this, α-ZrP is added to a Tris buffer solution and the mixture is ultrasonicated for 20 min.…”

Section: Synthesis and Preparation Of Zrp Nanomaterialsmentioning

confidence: 99%

Preparation of Zirconium Phosphate Nanomaterials and Their Applications as Inorganic Supports for the Oxygen Evolution Reaction

Ramos-Garcés

Colón

2020

Nanomaterials

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“…Inorganic inhibiting entities of the adsorption or oxidative types are majorly utilized in water-oriented PNC coatings [9] , while organic inhibiting entities are utilized for solvent based PNC nanocoatings [10] . The adhering behavior of PNC coatings is a critical parameter in achieving strong covering power [9] , [10] , [11] .…”

Section: Pnc Coatings Properties and Classificationmentioning

confidence: 99%

“…PNC coatings are composed of two or more entities in the nanoscale. As a result of inherently fine dimension of nanoparticles used in PNC coatings, void-filling and corrosive entities inhibition from penetrating surface of protected substrate enhances the coating efficiency [11] , [12] , [13] .…”

Section: Pnc Coatings Properties and Classificationmentioning

confidence: 99%

Recently Emerging Nanotechnological Advancements in Polymer Nanocomposite Coatings for Anti-corrosion, Anti-fouling and Self-healing

Idumah

Obele

Emmanuel

et al. 2020

Surfaces and Interfaces

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“…Among these methods, the hydrothermal method has the advantage of resulting in highly crystalline layered α-ZrP structures with a narrow particle size distribution and controlled morphology [ 9 ]. α-ZrP has gained a considerable interest owing to the ease of controlling its structure and facile exfoliation into few or single-layered entities with all the consequent possibilities of enhancing its intercalation capacity and increasing tremendously its surface area to mass ratio [ 10 , 11 , 12 , 13 , 14 , 15 , 16 ].…”

Section: Introductionmentioning

confidence: 99%

Nanolayered Metal Phosphates as Biocompatible Reservoirs for Antimicrobial Silver Nanoparticles

et al. 2021

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There is an increasing demand on synthesizing pharmaceuticals and biomaterials that possess antimicrobial and/or antiviral activities. In this respective silver nanoparticles are known for their excellent antimicrobial activity. Nevertheless, their uncontrolled release in a biological medium can induce a cytotoxic effect. For this, we explored the use of nanolayered metal phosphates based on titanium and zirconium as materials that can be enriched with silver nanoparticles. Employing the hydrothermal route, crystalline α-phases of zirconium and titanium phosphates (α-ZrP, α-TiP) were synthesized and there after surface-enriched with silver nanoparticles. The structural assessment confirmed the stability of the structures and their sizes are in the nanoscale at least in one dimension. The cytocompatibility assays confirmed the biocompatibility of the pristine phases and the antimicrobial assay confirmed that both silver-enriched nanolayered structures maintain an antibacterial effect at reasonably low concentrations.

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Exfoliation and functionalization of α-zirconium phosphate in one pot for waterborne epoxy coatings with enhanced anticorrosion performance

Cited by 43 publications

References 57 publications

Preparation of Zirconium Phosphate Nanomaterials and Their Applications as Inorganic Supports for the Oxygen Evolution Reaction

Preparation of Zirconium Phosphate Nanomaterials and Their Applications as Inorganic Supports for the Oxygen Evolution Reaction

Recently Emerging Nanotechnological Advancements in Polymer Nanocomposite Coatings for Anti-corrosion, Anti-fouling and Self-healing

Nanolayered Metal Phosphates as Biocompatible Reservoirs for Antimicrobial Silver Nanoparticles

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