Exergy Efficiency Promotion for the System of CO2 Hydrogenation to Methanol in Habitable Confined Space

Abstract

Excess hydrogen and carbon dioxide will be produced during the operation of life support systems in the habitable confined space (HCS), and to eliminate the two excess gases by converting them into methanol is of great significance for maintenance of atmospheric balance and protection of crew’s life safety. Due to the limited energy supply ability within the HCS, it is important for the system of carbon dioxide hydrogenation to methanol (CDHM) to operate with high energy efficiency to reduce unnecessary external energy consumption and internal energy loss. In this paper, the exergy analysis method is adopted for exergy efficiency improvement. Specifically, a parametric study on the exergetic performance of the CDHM system is conducted based on the three key working condition parameters that have a huge impact on the reaction process and energy utilization quality, which is used to find the favorable working condition with low external energy consumption and exergy destruction per unit gas elimination and high exergy efficiency. Within the chosen three reaction parameters which are reaction pressure, temperature, and space velocity ranging from 5 to 8 MPa, from 483.15 to 543.15 K, and from 2,800 to 4000 h−1, respectively, the gas elimination of carbon dioxide and hydrogen increases by 13.3, 19.58, and 30.58%, respectively. Moreover, the input power, cold energy consumption, and exergy destruction per molar synthetic methanol all grow to some extent, leading to a 0.06% decline, a 0.46% promotion, and a 0.15% decrease, respectively, in the exergy efficiency. The results show that the high exergy efficiency can be realized with relatively low pressure, high temperature, and low space velocity in the working condition. Besides, the exergy destructions of each component in the CDHM system are also presented in this paper. The exergy destructions in the methanol synthesis reactor, heater, and heat exchanger hot end are found to be the three biggest, whose summation accounts for more than 90% of the total system exergy destruction. Thus, the exergy efficiency also can be improved by reducing the three biggest exergy destructions.

Quo Vadis Dry Reforming of Methane?—A Review on Its Chemical, Environmental, and Industrial Prospects

“…However, the high barrier to activating CO 2 requires high reaction temperatures and may thus require a larger energy input compared to SRM. Additionally, the different routes of CO 2 hydrogenation leading to CO, methanol, and hydrocarbons such as methane can be used for economic comparisons [66,67]. A study in 2016 assessed that the cost of methanol production in Germany by electrical power approaches varied between €608 and €1453 per ton.…”