Excitation dependent white and red-NIR emission of a Mn^II-based complex

Abstract

Nowadays, the organic and organic-inorganic supramolecular crystals are potential candidates for lighting applications. In this work, a new molecular crystal (C5H8N3)2[MnCl4(C5H7N3)2] abbreviated (AmpH)2[MnCl4(Amp)2], (C5H7N3 = Amp = 2-amino-4-methylpyrimidine), containing octahedral...

Assembly of a cadmium(ii)-based chiral complex: crystal structure and optical properties for solid state white-light emission applications

“…More crucially, HSs and 2D FPs analyses allow us to evaluate all non-covalent interactions created by the molecule in concern, which offers a good way to study more all the interactions present in the crystalline structures. 47,48…”

“…More crucially, HSs and 2D FPs analyses allow us to evaluate all non-covalent interactions created by the molecule in concern, which offers a good way to study more all the interactions present in the crystalline structures. 47,48 The goal of this investigation is to discover and quantify the variations in contact contributions to the HS for this complex. Studying the dnorm-mapped HS of [Cd(Br) 2 (S-NA) 2 ] reveals two separate areas with different numbers and types of intermolecular interactions (Fig.…”