Exciplex-driven blue OLEDs: unlocking multifunctionality applications

Abstract

We present the development of multifunctional blue-emission organic light-emitting diodes (OLEDs) using TADF-exciplex materials. These OLEDs exhibit sensitivity to external stimuli and achieve a maximum external quantum efficiency (EQE) of 11.6% through partly liquid processing. This technique allows for large-scale production on arbitrary geometries.The potential multifunctionality of the devices arises from their response to low external magnetic fields (up to 100 mT) with an efficiency up to 2.5% for magnetoconductance, while maximum magneto-electroluminescence effects of 4.1% were detected. We investigated novel aspects, including the utilization of two organic materials without further doping and the investigation of the impact of 2,2ʹ,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) processing in liquid and vapor form. The insights gained provide a fundamental understanding regarding the applicability of exciplex (EX) materials for fully solution-processed OLEDs through a deliberate omission of doping. Our work represents a significant advancement on the path towards multifunctional OLED technology, with potential applications in cost-efficient, scalable organic full-color displays and advanced sensing system.