The particle continuity equations for H+ and O+ and the energy continuity equation are solved simultaneously by means of a computer program. The processes included are photo‐ionization, charge exchange, ambipolar diffusion along magnetic field lines, heat conduction, local and nonlocal heating, and heat loss from ions to neutrals. The ion composition and plasma temperature along various field lines are derived and studied by adopting electron concentration and temperature measurements from Explorer 22 (1000‐km altitude, 1965 vernal equinox) as boundary conditions. The O+ — H+ transition region at middle and low latitudes is fully described. It is found that a neutral hydrogen concentration of 2 × 105/cm³ at 500 km is required to make the calculated electron concentration consistent with satellite measurements of electron concentration at 650 km. A latitudinal variation of the ion composition arises primarily because of the latitudinal variation of the electron temperature. The temperature gradient along field lines is found to be a function of latitude. The temperature decreases along the equatorial field line that passes through the equator at 1000 km, and it increases along midlatitude field lines. This is consistent with the equatorial trough of the electron temperature evident in Explorer 22 data and thus explains to some degree the latitudinal variation of the ion composition.