“…There are only a few other examples in the literature concerning H E curves of M or S shape for binary mixtures of aromatics + polar components. 8,9 As discussed previously, 1 the exothermal effect in the binary mixtures of the three lactones + benzene depends strongly on steric factors, because their dipole moments are almost equal. 2 The shape and size of the molecules appear most favorable for attractive interactions between benzene and lactone molecules.…”
Section: Discussionmentioning
confidence: 82%
“…This gives an S-shaped curve to this system too. There are only a few other examples in the literature concerning H E curves of M or S shape for binary mixtures of aromatics + polar components. , …”
Molar excess enthalpies of binary liquid mixtures of γ-valerolactone or δ-valerolactone + benzene, +
toluene, or + ethylbenzene were measured by means of a flow microcalorimeter of Picker type at 293.15
K and atmospheric pressure.
“…There are only a few other examples in the literature concerning H E curves of M or S shape for binary mixtures of aromatics + polar components. 8,9 As discussed previously, 1 the exothermal effect in the binary mixtures of the three lactones + benzene depends strongly on steric factors, because their dipole moments are almost equal. 2 The shape and size of the molecules appear most favorable for attractive interactions between benzene and lactone molecules.…”
Section: Discussionmentioning
confidence: 82%
“…This gives an S-shaped curve to this system too. There are only a few other examples in the literature concerning H E curves of M or S shape for binary mixtures of aromatics + polar components. , …”
Molar excess enthalpies of binary liquid mixtures of γ-valerolactone or δ-valerolactone + benzene, +
toluene, or + ethylbenzene were measured by means of a flow microcalorimeter of Picker type at 293.15
K and atmospheric pressure.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.