Excess energy–volume and cohesive energy density coefficients for binary systems. Comparison with constant pressure functions

Abstract

DIGBY D. MACDONALD. Can. J. Cheni. 54, 3559 (1976). Excess energy-volume and cohesive energy density coefficients have been calculated for the hexane 4-perfluoro-hexane, water + DMSO, water + rert-butanol, water f methanol, water + acetonitrile. and methanol + DMSO systems. These parameters are compared with other constant pressure excess functions of mixing for these binary systerns, and it is proposed that they represent additional criteria for the classification of liquid mixtures. [Traduit par le journal]