1989
DOI: 10.1016/0022-328x(89)87076-7
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EXAFS infrared and kinetic studies on a ruthenium carbonyl hydroformylation system

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Cited by 17 publications
(2 citation statements)
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“…Among the oxo catalysts other than Co and Rh complexes, phosphine-platinum carbonyls modified with SnCl 2 [18], and ruthenium carbonyl clusters (Ru 3 (CO) 12 or Ru 4 H 4 (CO) 12 ) in the presence of strong bases (NaOH, NR 3 , NaBH 4 , I − ) [28][29][30] are the most extensively studied systems. The catalytic activities here are attributed to the carbonyl hydrides PtH(CO)(SnCl 3 )PR 3 and [RuH(CO) 4 ] − , respectively.…”
Section: Catalysts Other Than Cobalt and Rhodium Compoundsmentioning
confidence: 99%
“…Among the oxo catalysts other than Co and Rh complexes, phosphine-platinum carbonyls modified with SnCl 2 [18], and ruthenium carbonyl clusters (Ru 3 (CO) 12 or Ru 4 H 4 (CO) 12 ) in the presence of strong bases (NaOH, NR 3 , NaBH 4 , I − ) [28][29][30] are the most extensively studied systems. The catalytic activities here are attributed to the carbonyl hydrides PtH(CO)(SnCl 3 )PR 3 and [RuH(CO) 4 ] − , respectively.…”
Section: Catalysts Other Than Cobalt and Rhodium Compoundsmentioning
confidence: 99%
“…Compound 8 is very soluble in CH,Cl, and thf and moderately soluble in non-polar organic solvents and MeOH. IR: v(C0) (cyclohexane) 2056s, 2 0 2 2 5 2 0 0 6 ~ 1993s, 1986m, 1972(sh), 1962s, 1951m, 1942(sh) [10][11][12][13][14]. Two check reflections showed no decay during the experiment and an empirical y-scan absorption correction based on three reflections was applied (transmission: minimum 86.7, maximum 100.0%) as well as Lorentz and polarisation corrections.…”
Section: : 2 ~~H ;mentioning
confidence: 99%