2016
DOI: 10.1103/physrevb.93.125102
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Evolution of the charge density wave superstructure inZrTe3under pressure

Abstract: The material ZrTe 3 is a well-known example of an incommensurate periodic lattice distortion (PLD) at low temperatures due to a charge density wave (CDW). Previous studies have found a sharp boundary as a function of pressure between CDW below 5 GPa and bulk superconductivity above this value. We present a study of low-temperature-high-pressure single crystal x-ray diffraction along with ab initio density functional theory calculations. The modulation vector q CDW is found to change smoothly with pressure unti… Show more

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Cited by 25 publications
(33 citation statements)
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References 26 publications
(32 reference statements)
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“…4b is different from this but Se could act as a chemical pressure due to its smaller size. Therefore slight increase in band filling of the quasi-1D Fermi surface sheet seen in pure ZrTe 3 under pressure could be the mechanism for the in-plane anisotropy and promotion of SC 29 . However, due to very small Se content (up to about 3 atomic %) and no appreciable change in the unit cell parameters, this would imply strong sensitivity of CDW to substitutions on Te site and possibly to disorder.…”
Section: Discussionmentioning
confidence: 95%
“…4b is different from this but Se could act as a chemical pressure due to its smaller size. Therefore slight increase in band filling of the quasi-1D Fermi surface sheet seen in pure ZrTe 3 under pressure could be the mechanism for the in-plane anisotropy and promotion of SC 29 . However, due to very small Se content (up to about 3 atomic %) and no appreciable change in the unit cell parameters, this would imply strong sensitivity of CDW to substitutions on Te site and possibly to disorder.…”
Section: Discussionmentioning
confidence: 95%
“…This is also supported by the evolution of q CDW , which remains constant rather than changing as under hydrostatic pressure. 5 The Ni site is unambiguously identified as an intercalation site in the van-der-Waals gap with a five-fold coordinated site directly above a Zr atom being energetically favourable over a similar site above a link between (ZrTe 3 ) ∞ chains.…”
Section: Discussionmentioning
confidence: 99%
“…Our data show furthermore that the modulation q CDW is not changing with Ni content, while a rotation and change of size of q CDW was observed under hydrostatic pressure. 5 The small change of lattice constant (∼ +0.3% of unit cell volume change), compared to −8% up to 5 GPa pressure, is indicative that chemical pressure plays a minor role in the quenching of the CDW. Instead the local buckling of the Te sheet close to the van-der-Waals gap, adjacent to the Ni defect [ Fig.3(b)] is likely to have a strong effect on the long range order of the CDW by pinning.…”
Section: Discussionmentioning
confidence: 99%
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“…This scenario suggests that the compression-induced disorder destroys the perfection of Fermi surface nesting and suppresses the CDW. [34,35] As shown in Figure 3b, the resistive superconducting transition demonstrates an anomalous two-step feature with T 1 and T 2 being the onset critical temperatures of the two steps, respectively. To gain insight into the two-step resistive superconducting transition, we measured R(T) in different magnetic fields, µ 0 H (Figure 3c).…”
mentioning
confidence: 93%