2021
DOI: 10.3390/cryst11010072
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Evolution of Shape and Volume Fraction of Superconducting Domains with Temperature and Anion Disorder in (TMTSF)2ClO4

Abstract: In highly anisotropic organic superconductor (TMTSF)2ClO4, superconducting (SC) phase coexists with metallic and spin-density wave phases in the form of domains. Using the Maxwell-Garnett approximation (MGA), we calculate the volume ratio and estimate the shape of these embedded SC domains from resistivity data at various temperature and anion disorder, controlled by the cooling rate or annealing time of (TMTSF)2ClO4 samples. We found that the variation of cooling rate and of annealing time affect differently … Show more

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Cited by 7 publications
(5 citation statements)
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References 74 publications
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“…It is also worth noting the possibility of indirectly experimental confirmation of the spatial phase separation, often associated with phase transitions of the first kind, on the temperature dependence of resistance anisotropy. The conductivity theory in heterogeneous materials [20], applied to highly anisotropic materials [21][22][23][24][25][26], indicates a specific dependence of resistance anisotropy, which can give information about the approximate shape and size of the islets of one phase in the matrix of the other, for example, metal or any well-conducting phase in the material with CDW.…”
Section: Discussion Of Possible Further Experimental Confirmations An...mentioning
confidence: 99%
“…It is also worth noting the possibility of indirectly experimental confirmation of the spatial phase separation, often associated with phase transitions of the first kind, on the temperature dependence of resistance anisotropy. The conductivity theory in heterogeneous materials [20], applied to highly anisotropic materials [21][22][23][24][25][26], indicates a specific dependence of resistance anisotropy, which can give information about the approximate shape and size of the islets of one phase in the matrix of the other, for example, metal or any well-conducting phase in the material with CDW.…”
Section: Discussion Of Possible Further Experimental Confirmations An...mentioning
confidence: 99%
“…A first method based on combined transport and diamagnetic-response measurements in bulk material has been proposed recently and applied to analyze the SC heterogeneity in several strongly anisotropic materials, including FeSe [28,29], YBa 2 Cu 4 O 8 [30], and several organic superconductors [30,31,34]. These materials have a layered crystal structure and, hence, a strong anisotropy of electronic properties, common to all ambient-pressure high-Tc superconductors.…”
Section: The Origin Of Anisotropic Resistivity Drop Above T C and Max...mentioning
confidence: 99%
“…A new method, based on combined transport and diamagnetic-response measurements in bulk material, was recently suggested and applied to study the SC heterogeneity in several strongly anisotropic materials, including FeSe [32,33], YBa 2 Cu 4 O 8 [34], and several organic superconductors [34][35][36]. These materials have a layered crystal structure and, hence, a strong anisotropy of electronic properties, which is typical of all ambientpressure high-T c superconductors.…”
Section: The Origin Of Anisotropic Resistivity Drop Above T C and The...mentioning
confidence: 99%
“…Hence, it would be very useful to study SC inhomogeneity deep inside the bulk sample. Although less visual, two such methods based on combined transport and diamagnetic-response measurements in bulk and finite-size samples were proposed recently [32][33][34][35][36][37], as described in the next section. The scenario of inhomogeneous SC onset in the form of isolated islands is supported by anisotropic excess conductivity in FeSe above T c , measured in Ref.…”
Section: Introductionmentioning
confidence: 99%