Evidence for the formation of boron nitride-alkali metal intercalation compounds

Freeman, A. G.; Larkindale, J. P.

doi:10.1016/0020-1650(69)80016-4

Cited by 14 publications

(4 citation statements)

References 2 publications

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“…Intercalation and its related functions have been widely studied for graphite. In the case of h-BN, intercalation with alkali-metal atoms, [43][44][45] transition-metal atoms, 46 and molecules such as Br 2 ͑Ref. 44͒ and S 2 O 6 F 2 ͑Ref.…”

Section: Isolatedmentioning

confidence: 99%

Doping of hexagonal boron nitride via intercalation: A theoretical prediction

et al. 2010

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A doping strategy for hexagonal boron nitride ͑h-BN͒ is proposed through hybrid Hartree-Fock density functional calculations. Unlike their behavior in typical semiconductors, substitutional dopants generate deep and localized in-gap states in h-BN. In contrast, intercalated atoms with high and low electronegativities perturb the host valence and conduction bands weakly, resulting in shallow acceptor and donor states, respectively. The formation of defect complexes involving substitutional dopants suppresses the migration of the intercalated dopants, with the shallow acceptor or donor characteristics preserved. The strategy proposed here is also applicable to h-BN ultrathin layers and extendable to the doping of BN single sheets via adsorption.

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Section: Isolatedmentioning

confidence: 99%

Doping of hexagonal boron nitride via intercalation: A theoretical prediction

et al. 2010

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“…and Stumpp (3). Freeman and Larkindale (4,5) reported that a pink product from the interaction of h-BN with FeCl was accompanied by a small expansion of the interlayer spacing, but Ohashi and Shinjo (6) made an extensive study of this system and concluded that the pink material was due to a surface hydrolysis product, FeOCl. Reductive intercalation of h-BN by alkali metals has also been claimed, (7) but not substantiated (8).…”

Section: Had Claimed a Variety Of Intercalation Compounds Involving mentioning

confidence: 99%

Intercalation of Hexagonal Boron Nitride by Strong Oxidizers and Evidence for the Metallic Nature of the Products

Shen

Mayorga

Biagioni

et al. 1999

Journal of Solid State Chemistry

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“…Based on this study, the calculated formation enthalpy of the considered forms of Li intercalated BN is found to be positive that eliminates BN interaction without externally supplied energy. In [31], Freeman and Larkindale have also discussed that BN powder reacts with sodium and potassium. Accordingly, the interaction of BN film with potassium is so that charge transfer between the potassium and BN bonds is very small.…”

Section: Introductionmentioning

confidence: 99%

Interaction of hydrogen-edged boron nitride flakes with lithium: boron nitride as a protecting layer for a lithium-ion battery and a spin-dependent photon emission device

Kheirabadi

Shafiekhani²

2021

Nanotechnology

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The current rechargeable battery technologies have a failure in their performance at high pressure and temperature. In this article, we have brought theoretical insights on using boron nitride flakes as a protecting layer for a lithium-ion battery device and extended its application for a spin-dependent photon emission device. Hence, the electronic properties of pristine and lithium-doped hydrogen-edged boron nitride flakes have been studied by the first principle density functional theory calculations. In this study, we have discussed the stability, adsorption energies, bond lengths, electronic gaps, frontier molecular orbitals, the density of states, charge distributions, and dipole moments of pristine and lithium hydrogen-edged doped boron nitride flakes.

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Evidence for the formation of boron nitride-alkali metal intercalation compounds

Cited by 14 publications

References 2 publications

Doping of hexagonal boron nitride via intercalation: A theoretical prediction

Doping of hexagonal boron nitride via intercalation: A theoretical prediction

Intercalation of Hexagonal Boron Nitride by Strong Oxidizers and Evidence for the Metallic Nature of the Products

Interaction of hydrogen-edged boron nitride flakes with lithium: boron nitride as a protecting layer for a lithium-ion battery and a spin-dependent photon emission device

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