“…Many experiments have been carried out for Pr@Ba on samples of Pr123 [6, 9 -12], Y123 [13,14], Sm123 [12], Eu123 [15,16], Gd123 [17], and other rare earth elements R@Ba such as La and Eu@Ba in Pr123 [18], La@Ba in Y123 [14], or in Pr123 [4], Nd@Ba in Nd123 [13,19], Ho,Y and Ca@Pr in Pr123 [20], Ba@Pr in Pr123 [21,22]. Through these experiments different structural and valence modifications related to Pr are reported.…”