Sodium ion batteries are attractive alternatives to lithium ion batteries for stationary energy storage technology, and titanates are considered as promising anode materials for sodium ion batteries. Herein, a series of sodium titanates were synthesized via a simple, fast and controllable electrochemical route from solid TiO2 in molten salts of NaF-NaCl-NaI. For the first time, the as-prepared Na0.23TiO2 and Na0.46TiO2 were utilized as anode materials for sodium ion batteries, with the sodium storage capacity of 185 m Ah g -1 and 215 mA h g -1 after 200 cycles, respectively. High rate and long term tests indicated the excellent cycle performance due to the formation of 3D porous electrode structure during the long term charge/discharge processes. [24][25][26][27] Herein, for the first time, we reported a simple, fast and controllable synthesis of sires of sodium titanates (Na 0.23 TiO 2 , Na 0.46 TiO 2 , NaTi 2 O 4 ) via electrolysis of solid TiO 2 in molten salts of NaF-NaCl-NaI. The structure and morphology of as-prepared