Abstract:Fused deposition modeling (FDM) is a rapidly growing additive manufacturing technology due to its ability to manufacture complex‐shaped parts in a simple process. FDM parts present inherent porosity due to the fabrication process. The mechanical performance of the built part depends on controlling several printing parameters of the specimen and the quantity of voids. PLA/PBAT [polylactic acid/poly(butylene adipate‐co‐terephthalate)] blend is a biodegradable polyester with bio‐based content that is used as a po… Show more
“…The improvement of mechanical properties of PLA attained by blending with PBAT or PBSA, as well by addition of nanofillers, pushed development of these materials as filaments for 3D printing. PLA/PBAT and PLA/PBSA blends were investigated by a number of researchers, to test their suitability as 3D printing material, either as binary blends, or as compatibilized formulations [181][182][183][184], as well as containing micro-and nanofillers [185][186][187].…”
Section: Applications Of Pla/pbsa and Pla/pbat Blends And Nanocompositesmentioning
Poly(lactic acid) (PLA) is the most widely produced biobased, biodegradable and biocompatible polyester. Despite many of its properties are similar to those of common petroleum-based polymers, some drawbacks limit its utilization, especially high brittleness and low toughness. To overcome these problems and improve the ductility and the impact resistance, PLA is often blended with other biobased and biodegradable polymers. For this purpose, poly(butylene adipate-co-butylene terephthalate) (PBAT) and poly(butylene succinate-co-butylene adipate) (PBSA) are very advantageous copolymers, because their toughness and elongation at break are complementary to those of PLA. Similar to PLA, both these copolymers are biodegradable and can be produced from annual renewable resources. This literature review aims to collect results on the mechanical, thermal and morphological properties of PLA/PBAT and PLA/PBSA blends, as binary blends with and without addition of coupling agents. The effect of different compatibilizers on the PLA/PBAT and PLA/PBSA blends properties is here elucidated, to highlight how the PLA toughness and ductility can be improved and tuned by using appropriate additives. In addition, the incorporation of solid nanoparticles to the PLA/PBAT and PLA/PBSA blends is discussed in detail, to demonstrate how the nanofillers can act as morphology stabilizers, and so improve the properties of these PLA-based formulations, especially mechanical performance, thermal stability and gas/vapor barrier properties. Key points about the biodegradation of the blends and the nanocomposites are presented, together with current applications of these novel green materials.
“…The improvement of mechanical properties of PLA attained by blending with PBAT or PBSA, as well by addition of nanofillers, pushed development of these materials as filaments for 3D printing. PLA/PBAT and PLA/PBSA blends were investigated by a number of researchers, to test their suitability as 3D printing material, either as binary blends, or as compatibilized formulations [181][182][183][184], as well as containing micro-and nanofillers [185][186][187].…”
Section: Applications Of Pla/pbsa and Pla/pbat Blends And Nanocompositesmentioning
Poly(lactic acid) (PLA) is the most widely produced biobased, biodegradable and biocompatible polyester. Despite many of its properties are similar to those of common petroleum-based polymers, some drawbacks limit its utilization, especially high brittleness and low toughness. To overcome these problems and improve the ductility and the impact resistance, PLA is often blended with other biobased and biodegradable polymers. For this purpose, poly(butylene adipate-co-butylene terephthalate) (PBAT) and poly(butylene succinate-co-butylene adipate) (PBSA) are very advantageous copolymers, because their toughness and elongation at break are complementary to those of PLA. Similar to PLA, both these copolymers are biodegradable and can be produced from annual renewable resources. This literature review aims to collect results on the mechanical, thermal and morphological properties of PLA/PBAT and PLA/PBSA blends, as binary blends with and without addition of coupling agents. The effect of different compatibilizers on the PLA/PBAT and PLA/PBSA blends properties is here elucidated, to highlight how the PLA toughness and ductility can be improved and tuned by using appropriate additives. In addition, the incorporation of solid nanoparticles to the PLA/PBAT and PLA/PBSA blends is discussed in detail, to demonstrate how the nanofillers can act as morphology stabilizers, and so improve the properties of these PLA-based formulations, especially mechanical performance, thermal stability and gas/vapor barrier properties. Key points about the biodegradation of the blends and the nanocomposites are presented, together with current applications of these novel green materials.
“…Though the biodegradability of the blends of PLA and PBAT is not as good as that of the pure polymers [ 20 ], blends can be manufactured by using a coupling agent to ease chemical miscibility [ 21 , 22 ]. The printability of such blends has been investigated and proven, e.g., by Cardoso et al [ 23 ]. Regarding the high potential of bio-based and biodegradable polymers, auxetic structures manufactured from these materials could be used in, e.g., healthcare applications.…”
Auxetic structures have a negative Poisson’s ratio and therefore expand transversely to the direction of loading instead of tapering. This unique behavior is not caused by the materials used, but by the structure, and thus offers completely new functionalities and design possibilities. As a rule, auxetic structures have a very complex geometry, which makes cost-effective production possible only by means of additive manufacturing processes. Due to the high design freedom of the strand deposition method, it makes sense to manufacture auxetic structures using this process. Therefore, in this project, polylactide acid (PLA), polybutylene adipate terephthalate (PBAT), and blends of the two polymers were produced and characterized. Filaments of the two polymers and a blend were extruded, processed into auxetic structures by strand deposition process (SDP), and investigated for their properties, primarily their Poisson’s ratio. The Poisson’s ratio was determined and the influence of the material on it was identified. A specific number of 5 × 5 unit cells has been found to be ideal for investigation. Dual printed specimens showed a similar auxetic behavior as the specimens made of pure PBAT. Likewise, multiple loading and unloading of the structure is possible. Furthermore, in-situ computed tomography revealed the detailed characterization of the initial state, including the warpage of the structures, damage, and traced auxetic behavior in detail.
“…These discontinuities and/or voids can be associated with the deposition of the filament in layers in the formation of the part. During deposition, gaps may be partially filled (pores) due to incomplete diffusion into adjacent strands in some parts, and slight agglomeration or saturation of the filling may be observed [ 22 , 39 ].…”
Section: Resultsmentioning
confidence: 99%
“…Allied to the use of biodegradable plastics for sustainability, industry 4.0 presents itself as a crucial tool in increasing productivity and efficiency in the planning and control of products in several segments, with agricultural development being the most recent. Additive manufacturing, one of the pillars of this new industry, comprises a low-cost, efficient, easy-to-operate production technique which provides a wide variety of materials that can be used in versatile applications [ 22 , 23 , 24 ] ranging from biomedical, automotive and aerospace applications as well as prototyping industries in general [ 25 ].…”
The aim of this work was to produce filaments of PLA/PBAT and NPK fertilizer adsorbed on organophilized bentonite intended for application in the prototyping of biodegradable agricultural artifacts in 3D printing, using the Fused Deposition Modeling (FDM) technique. This is the first time that we have reported this composite for a 3D printing approach. Systems containing PLA/PBAT, organobentonite and NPK were initially processed in an internal mixer and later extruded as filaments in a single-screw extruder. The prototypes were printed by FDM. Structural, morphological and thermal properties, as well as NPK releasing, were investigated. The results suggest that exfoliated and/or intercalated nanocomposites were obtained by the organoclay addition to the PLA/PBAT blend. The morphological analysis revealed a good surface quality of the impressions. Systems containing organobentonite released approximately 22% less fertilizer in 24 h compared to the systems without organobentonite. This difference is due to the higher concentration of nanoparticles that generate more barriers to the diffusion of NPK. The release data for these systems had a better fit to the kinetic model of Korsmeyer-Peppas. Thus, studied filaments have the potential to retard the release of fertilizer and are suitable for further development of structures for agricultural applications by FDM.
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