Unconventional oil and natural gas
(UONG) exploration and production
have grown rapidly and are expected to increase further in the United
States and internationally. Direct measurements of key air pollutant
emissions from UONG are limited, especially during drilling and completion
(hydraulic fracturing and flowback) of new wells. Knowledge of emission
rates (ERs) of air toxics and other air pollutants from these activities
is urgently needed to inform public policy. To address this key knowledge
gap, we use a tracer ratio method to quantify pad-level, activity-specific
[drilling, hydraulic fracturing (“fracking”), flowback,
and production] ERs of 46 VOCs in the Denver-Julesburg (D-J, a mixed
oil and gas play) and Piceance (primarily natural gas) basins in Colorado.
Large differences in ERs of individual VOCs were observed across operation
types, across facilities conducting the same operation type, and over
time during a single operation. ERs of benzene and most VOCs were
highest in both basins during flowback, when injected fracking fluids
and produced water flow to the surface. ERs from production are much
lower, an important result given the significant difference in the
duration of activity (days to weeks for flowback vs decades for production).
Fracking ERs of light alkanes and benzene were higher in the Piceance
Basin than in the D-J Basin. Findings from this study provide important
new information that can be used to evaluate potential health hazards
and other air quality impacts of unconventional oil and gas activities
in Colorado’s two major oil and gas production basins.