Some studies have suggested that variations in the seasonal cycle of temperature and season onset could affect the efficiency in the use of radiation by plants, which would then affect yield. However, the study of the temporal variation in extreme climatic variables is not sufficient in China. Using seasonal trend analysis (STA), this article evaluates the distribution of extreme temperature seasonality trends in mainland China, describes the trends in the seasonal cycle, and detects changes in extreme temperature characterized by the number of hot days (HD) and frost days (FD), the frequency of warm days (TX90p), cold days (TX10p), warm nights (TN90p), and cold nights (TN10p). The results show a statistically significant positive trend in the annual average amplitudes of extreme temperatures. The amplitude and phase of the annual cycle experience less variation than that of the annual average amplitude for extreme temperatures. The phase of the annual cycle in maximum temperature mainly shows a significant negative trend, accounting for approximately 30% of the total area of China, which is distributed across the regions except for northeast and southwest. The amplitude of the annual cycle indicates that the minimum temperature underwent slightly greater variation than the maximum temperature, and its distribution has a spatial characteristic that is almost bounded by the 400 mm isohyet, increasing in the northwest and decreasing in the southeast. In terms of the extreme air temperature indices, HD, TX90p, and TN90p show an increasing trend, FD, TX10p, and TN10p show a decreasing trend. They are statistically significant (p < 0.05). This number of days also suggests that temperature has increased over mainland China in the past 42 years.