Based on effective field method, the dynamic effective elastic modulus of polymer matrix composites embedded with dense piezoelectric nano-fibers is obtained, and the interacting effect of piezoelectric surfaces/interfaces around the nano-fibers is considered. The multiple scattering effects of harmonic anti-plane shear waves between the piezoelectric nano-fibers with surface/interface are averaged by effective field method. To analyze the interacting results among the random nano-fibers, the problem of two typical piezoelectric nano-fibers is introduced by employing the addition theorem of Bessel functions. Through numerical calculations, the influence of the distance between the randomly distributed piezoelectric nano-fibers under different surface/interface parameters is analyzed. The effect of piezoelectric property of surface/interface on the effective shear modulus under different volume fractions is also examined. Comparison with the simplified cases is given to validate this dynamic electro-elastic model. piezoelectric nanocomposites, dense nano-fibers, dynamic effective properties, effective field method PACS number(s): 42.70.Mp, 81.05.Ni, 62.25.+g, 62.30.+d Citation: Fang X Q, Huang M J, Zhu Z T, et al. Dynamic effective elastic modulus of polymer matrix composites with dense piezoelectric nano-fibers considering surface/interface effect. Sci China-Phys Mech Astron,