Abstract:The sintered zinc oxide (ZnO) electro-ceramics are a brittle class of hard-to-cut materials such that shaping them with the post-finishing operations necessitates careful handling and precision machining. The conventional machining approach using the grinding and lapping processes represents limited productivity, an inability to produce the required geometries and frequent uncontrolled chipping of the edges of the final products. This study thus investigates the turning performance of dense sintered ZnO varist… Show more
“…Mn doping reduced the mean ZnO grain size in all the ternary systems compared to undoped MOVs from ZnO-V2O5 systems, but the densification of the Mn3O4or MnO2-doped MOVs was almost equal, with a relative density (RD) of 94.6-96% of theoretical density (TD). These densities comply with the accepted values for commercial MOVs, with RD greater than 95% of TD, where TD is around 5.6-5.7 g/cm 3 [111].…”
Section: Structural Propertiessupporting
confidence: 88%
“…Additionally, the selected VFO and dopants [ 7 , 103 , 104 , 105 , 106 , 107 ] also play a crucial role. Furthermore, the techniques used for preparing MOV powder mixtures [ 108 , 109 ], as well as the consolidation (pressing of MOV powders) and densification techniques (sintering of MOV compacts) ( Figure 3 ), including post-annealing and post-processing techniques of MOVs [ 13 , 76 , 77 , 94 , 110 , 111 ], have a significant impact on the properties of MOVs.…”
Section: Overview Of the Development Of Zno-based Varistorsmentioning
confidence: 99%
“…The liquid phase can enhance GB mobility, but the formed intragrain pores can decrease the sintered density of MOVs [ 118 ]. Lower-density MOVs (RD < 95% of TD) can yield defects such as spherical holes, indicating inadequately joined grains, leading to a decrease in the mechanical strength of MOVs [ 111 ].…”
Section: Overview Of the Development Of Zno-based Varistorsmentioning
This article reviews the progress in developing ZnO-V2O5-based metal oxide varistors (MOVs) using powder metallurgy (PM) techniques. The aim is to create new, advanced ceramic materials for MOVs with comparable or superior functional properties to ZnO-Bi2O3 varistors using fewer dopants. The survey emphasizes the importance of a homogeneous microstructure and desirable varistor properties, such as high nonlinearity (α), low leakage current density (JL), high energy absorption capability, reduced power loss, and stability for reliable MOVs. This study investigates the effect of V2O5 and MO additives on the microstructure, electrical and dielectric properties, and aging behavior of ZnO-based varistors. The findings show that MOVs with 0.25–2 mol.% V2O5 and MO additives sintered in air over 800 °C contain a primary phase of ZnO with a hexagonal wurtzite structure and several secondary phases that impact the MOV performance. The MO additives, such as Bi2O3, In2O3, Sb2O3, transition element oxides, and rare earth oxides, act as ZnO grain growth inhibitors and enhance the density, microstructure homogeneity, and nonlinearity. Refinement of the microstructure of MOVs and consolidation under appropriate PM conditions improve their electrical properties (JL ≤ 0.2 mA/cm2, α of 22–153) and stability. The review recommends further developing and investigating large-sized MOVs from the ZnO-V2O5 systems using these techniques.
“…Mn doping reduced the mean ZnO grain size in all the ternary systems compared to undoped MOVs from ZnO-V2O5 systems, but the densification of the Mn3O4or MnO2-doped MOVs was almost equal, with a relative density (RD) of 94.6-96% of theoretical density (TD). These densities comply with the accepted values for commercial MOVs, with RD greater than 95% of TD, where TD is around 5.6-5.7 g/cm 3 [111].…”
Section: Structural Propertiessupporting
confidence: 88%
“…Additionally, the selected VFO and dopants [ 7 , 103 , 104 , 105 , 106 , 107 ] also play a crucial role. Furthermore, the techniques used for preparing MOV powder mixtures [ 108 , 109 ], as well as the consolidation (pressing of MOV powders) and densification techniques (sintering of MOV compacts) ( Figure 3 ), including post-annealing and post-processing techniques of MOVs [ 13 , 76 , 77 , 94 , 110 , 111 ], have a significant impact on the properties of MOVs.…”
Section: Overview Of the Development Of Zno-based Varistorsmentioning
confidence: 99%
“…The liquid phase can enhance GB mobility, but the formed intragrain pores can decrease the sintered density of MOVs [ 118 ]. Lower-density MOVs (RD < 95% of TD) can yield defects such as spherical holes, indicating inadequately joined grains, leading to a decrease in the mechanical strength of MOVs [ 111 ].…”
Section: Overview Of the Development Of Zno-based Varistorsmentioning
This article reviews the progress in developing ZnO-V2O5-based metal oxide varistors (MOVs) using powder metallurgy (PM) techniques. The aim is to create new, advanced ceramic materials for MOVs with comparable or superior functional properties to ZnO-Bi2O3 varistors using fewer dopants. The survey emphasizes the importance of a homogeneous microstructure and desirable varistor properties, such as high nonlinearity (α), low leakage current density (JL), high energy absorption capability, reduced power loss, and stability for reliable MOVs. This study investigates the effect of V2O5 and MO additives on the microstructure, electrical and dielectric properties, and aging behavior of ZnO-based varistors. The findings show that MOVs with 0.25–2 mol.% V2O5 and MO additives sintered in air over 800 °C contain a primary phase of ZnO with a hexagonal wurtzite structure and several secondary phases that impact the MOV performance. The MO additives, such as Bi2O3, In2O3, Sb2O3, transition element oxides, and rare earth oxides, act as ZnO grain growth inhibitors and enhance the density, microstructure homogeneity, and nonlinearity. Refinement of the microstructure of MOVs and consolidation under appropriate PM conditions improve their electrical properties (JL ≤ 0.2 mA/cm2, α of 22–153) and stability. The review recommends further developing and investigating large-sized MOVs from the ZnO-V2O5 systems using these techniques.
“…However, at feed rate v = 160 mm/min, the resultant slice roughness at the edges was trimmed down to 65 µm. This implies unsuitability of AWJ cutting at higher feed rates, as the edge regions and taper did not adhere to the principal electrical impulse testing requirements [30]. Further on, the comparison of surface roughness was also made by investigating the topographical color scans.…”
Sintered zinc oxide (ZnO) ceramic is a fragile and difficult-to-cut material, so finishing operations demand handling cautious and accurate surface tolerances by polishing, grinding, or machining. The conventional machining methods based on grinding and lapping offer limited productivity and high scalability; therefore, their incapacity to prepare tight tolerances usually end up with uncontrolled edge chipping and rough surfaces in the final products. This study investigates microstructural features with surface roughness in a comparative mode for conventional milling and abrasive waterjet cutting (AWJ). Edge topography and roughness maps are presented in this study to weigh the benefits of AWJ cutting over the conventional material removal methods by altering the feed rates. The porosity analysis implies that the differences during the multi-channel processing of varistors, which tend to alter the microstructure, should in turn exhibit a different response during cutting. The surface roughness, edge contours, and porosity generation due to shear forces are interpreted with the help of 3D optical and electron microscopy. The results demonstrate that the surface microstructure can have a noteworthy impact on the machining/cutting characteristics and functionality, and in addition, mechanical properties of ZnO varistors can fluctuate with non-uniform microstructures.
“…Before extensive study, preliminary experiments on turning of ZnO ceramics with PCD tools were performed and tool life, comparable to metal cutting was achieved. It was also concluded that the main factor reducing ZnO ceramics machinability is excessive machining-induced damage like grain pull-out and edge chipping [31]. A study using a conventional milling strategy, based on the turning parameters, yielding the best results, showed that surface microstructure can have a noteworthy impact on the machining characteristics of this material and substantially better surface roughness was achieved by abrasive waterjet machining [32].…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.