2011
DOI: 10.1016/j.enconman.2010.12.049
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Evaluation of a seasonal storage system of solar energy for house heating using different absorption couples

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Cited by 132 publications
(24 citation statements)
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“…The possibility of loss-free storage makes thermo-chemical fluids a promising opportunity for seasonal heat storages in solar-heated buildings. Sodium hydroxide solution is recommended as a suitable storage medium in various publications (Weber, 2008;Hui, 2008;Goetz, 2001; [9,10,11]), but cannot be used in open processes: the reaction of sodium hydroxide with the carbon dioxide of the air forms a poorly soluble sodium carbonate, which precipitates in solid form during cooling processes and therefore clog pipes and plant components. The plant components for regeneration (desorber-condenser) as well as those for utilisation of the chemical potential (evaporator-absorber) shall operate at a negative pressure specified by the temperature level (vapour pressure of the water).…”
Section: Use Of Chemical Potential In Open Processmentioning
confidence: 99%
“…The possibility of loss-free storage makes thermo-chemical fluids a promising opportunity for seasonal heat storages in solar-heated buildings. Sodium hydroxide solution is recommended as a suitable storage medium in various publications (Weber, 2008;Hui, 2008;Goetz, 2001; [9,10,11]), but cannot be used in open processes: the reaction of sodium hydroxide with the carbon dioxide of the air forms a poorly soluble sodium carbonate, which precipitates in solid form during cooling processes and therefore clog pipes and plant components. The plant components for regeneration (desorber-condenser) as well as those for utilisation of the chemical potential (evaporator-absorber) shall operate at a negative pressure specified by the temperature level (vapour pressure of the water).…”
Section: Use Of Chemical Potential In Open Processmentioning
confidence: 99%
“…Faster heat and mass transfer rates are possible with liquid absorption. Materials recently investigated include aqueous solutions of CaCl 2 [Quinnell et al, 2011], LiCl [Bales, 2006], NaOH , and KOH [Hui et al, 2011]. Hui et al compare absorption materials for use in low pressure (1.2 -4.2 kPa) absorption cycles and have reported theoretical material energy densities up to 476 kWh/m 3 [Hui et al, 2011], as shown in …”
Section: Liquid Absorptionmentioning
confidence: 99%
“…The mass of water that can be added and removed from the storage is function of the temperature and pressure in the system. To-date, sorption storage media have been selected primarily from commercially available materials, including physical adsorption of water vapor on porous molecular sieves, typically aluminosilicate zeolites [Jänchen , 2004 andJänchen , 2005], or silica gel, and absorption using aqueous lithium chloride (LiCl) [Bales, 2006], lithium bromide (LiBr) [Le Pierres et al, 2008], sodium hydroxide (NaOH) [Weber and Dorer, 2008], or calcium chloride (CaCl 2 ) [Hui et al, 2011]. Reported material energy densities, based on the enthalpy of sorption, are 130 to 780 kWh/m 3 [Hauer, 2008 andBales et al, 2008]).…”
Section: Overview Of Materialsmentioning
confidence: 99%
“…It presents interesting thermal properties. However, LiBr crystallizes in dihydrated form at the temperature of the storage tank surrounding (5-10°C) with a water content of 29 wt% of water [2][3][4][5]. In view of replacement of LiBr, it was selected six other salts according to their literature data on their hydrated forms at low temperature, their solubility in water and their low price.…”
Section: Introductionmentioning
confidence: 99%
“…In a previous study [2,3], it was proved that crystallization of the solution inside a storage tank was necessary to increase the storage density, and thus reduce the storage tank size and cost. Crystallization is possible due to a little circulation of fluid in the tank [4] and it must be reversible and controlled.…”
Section: Introductionmentioning
confidence: 99%