“…This also suggests that Ni + YSZ is not a very good anode for CO as the fuel. Indeed, it has been reported in the literature that the electrochemical reaction rate of CO is slower than that of H 2 by at least a factor of two [21]. Comparison of performance curves for H 2 -H 2 O mixtures with CO-CO 2 mixtures from Figures 5 and 6 shows that the lower performance with CO-CO 2 mixtures cannot be attributed entirely to concentration polarization.…”
Section: Fuel Composition Effects On Anode Polarizationmentioning
“…This also suggests that Ni + YSZ is not a very good anode for CO as the fuel. Indeed, it has been reported in the literature that the electrochemical reaction rate of CO is slower than that of H 2 by at least a factor of two [21]. Comparison of performance curves for H 2 -H 2 O mixtures with CO-CO 2 mixtures from Figures 5 and 6 shows that the lower performance with CO-CO 2 mixtures cannot be attributed entirely to concentration polarization.…”
Section: Fuel Composition Effects On Anode Polarizationmentioning
“…The Knudsen diffusion is only relevant in the electrodes. Moreover, molecular diffusion in the cathode is usually binary (because the oxidant is oxygen from air (assumed to be made up of only O 2 and N 2 )), while in the anode it may be binary or multicomponent, depending on the fuel mixture (for humidified [7] compared in 1D and 2D, the Dusty Gas model and the Stefan-Maxwell model, and found that at high hydrogen utilization and high current densities the Dusty Gas model was the most accurate in terms of validation against experimental results by Yakabe et al [31] in both 1D and 2D. As the average current density increased, the differences between the 2D Dusty Gas model and the other models became more prominent.…”
“…In the case of a multicomponent mixture flowing through a microchannel, an effective diffusion coefficient should include molecular and Knudsen effects, by using a Bosanquet-type approximation (Yakabe et al, 2000;Mu et al, 2008):…”
Section: Multicomponent Diffusion Modelmentioning
confidence: 99%
“…The molecular diffusion coefficient is derived from a binary diffusion coefficient D kl through the simplified formula (Yakabe et al, 2000):…”
In this paper a three-dimensional model for determination of a microreactor's length is presented and discussed. The reaction of thermocatalytic decomposition has been implemented on the base of experimental data. Simplified Reynolds-Maxwell formula for the slip velocity boundary condition has been analysed and validated. The influence of the Knudsen diffusion on the microreactor's performance has also been verified. It was revealed that with a given operating conditions and a given geometry of the microreactor, there is no need for application of slip boundary conditions and the Knudsen diffusion in further analysis. It has also been shown that the microreactor's length could be practically estimated using standard models.
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