SummaryThe Hanford double-shell tank (DST) system provides the staging location for waste that will be transferred to the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Specific WTP acceptance criteria for waste feed delivery describe the physical and chemical characteristics of the waste that must be met before the waste is transferred from the DSTs to the WTP. One of the more challenging requirements relates to the sampling and characterization of the undissolved solids (UDS) in a waste feed DST because the waste contains solid particles that settle and their concentration and relative proportion can change during the transfer of the waste in individual batches. A key uncertainty in the waste feed delivery system is the potential variation in UDS transferred in individual batches in comparison to an initial sample used for evaluating the acceptance criteria. To address this uncertainty, a number of smallscale mixing tests have been conducted as part of Washington River Protection Solutions' Small Scale Mixing Demonstration (SSMD) project to determine the performance of the DST mixing and sampling systems. A series of these tests have used a five-part simulant composed of particles of different size and density and designed to be equal or more challenging than AY-102 waste. This five-part simulant, however, has not been compared with the broad range of Hanford waste, and thus there is an additional uncertainty that this simulant may not be as challenging as the most difficult Hanford waste. The purpose of this study is to quantify how the current five-part simulant compares to all of the Hanford sludge waste, and to suggest alternate simulants that could be tested to reduce the uncertainty in applying the current testing results to potentially more challenging wastes.Comparison of the size and density of the particulate comprising the five-part SSMD simulant to that of the characterized Hanford sludge waste particulate was made using metrics for particle mobilization, suspension, settling, transfer line intake, and pipeline transfer where dependence on particle size and density may be different, including: The five-part SSMD simulant and Hanford sludge waste particulate is represented by particle size and density distributions (PSDDs). Based on comparison of calculated and measured settling velocities, the Hanford sludge waste particles are characterized by particle size distribution (PSD) techniques that likely includes primary particles, hard agglomerates, and soft agglomerates or flocs, and are characterized by particle density by assuming that all particles have a density equal to the UDS compound crystal density regardless of particle size.The results of this analysis show that, as designed, the five-part SSMD simulant is typically more challenging than the AY-102 waste except for the larger and more dense particulate of the most iv challenging PSDD type, regardless of which metric is considered. The five-part SSMD simulant is also typically more challenging than the waste composites with the...