Eugenol: extraction, properties and its applications on incorporation with polymers and resins—a review

Kerosenewala, Jainabh; Vaidya, Prakash D.; Ozarkar, Vedant; Shirapure, Yogita; More, Aarti P.

doi:10.1007/s00289-022-04414-9

Cited by 15 publications

(5 citation statements)

References 168 publications

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“…The incorporation of EUG in macromolecular structures is an efficient strategy for the development and prolonged use of this volatile active substance. Polymers and composites with incorporated eugenol molecules include polyesters, polyurethanes, polyacrylates, epoxy, and polyolefins [10]. They often exhibit good barrier properties and thus have applications in the coating and packaging industries.…”

Section: Introductionmentioning

confidence: 99%

Eugenol-Based Polymeric Materials—Antibacterial Activity and Applications

Kowalewska,

Majewska-Smolarek

2023

Antibiotics

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Eugenol (4-Allyl-2-methoxy phenol) (EUG) is a plant-derived allyl chain-substituted guaiacol, widely known for its antimicrobial and anesthetic properties, as well as the ability to scavenge reactive oxygen species. It is typically used as a mixture with zinc oxide (ZOE) for the preparation of restorative tooth fillings and treatment of root canal infections. However, the high volatility of this insoluble-in-water component of natural essential oils can be an obstacle to its wider application. Moreover, molecular eugenol can be allergenic and even toxic if taken orally in high doses for long periods of time. Therefore, a growing interest in eugenol loading in polymeric materials (including the encapsulation of molecular eugenol and polymerization of EUG-derived monomers) has been noted recently. Such active macromolecular systems enhance the stability of eugenol action and potentially provide prolonged contact with pathogens without the undesired side effects of free EUG. In this review, we present an overview of methods leading to the formation of macromolecular derivatives of eugenol as well as the latest developments and further perspectives in their pharmacological and antimicrobial applications.

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Section: Introductionmentioning

confidence: 99%

Eugenol-Based Polymeric Materials—Antibacterial Activity and Applications

Kowalewska,

Majewska-Smolarek

2023

Antibiotics

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“…Furan-based copolyester is a high-strength, versatile thermoplastic resin. It is a hygroscopic, transparent, amorphous substance formed during the conversion of polyester. , In this section, we have studied the synthesis conditions, viscosities, and molar weights of co-polyesters through scientific reports and briefly discussed some copolyesters; data are presented in Table .…”

Section: 5-fdca-based Copolyestersmentioning

confidence: 99%

Recent Progress on Sustainable 2,5-Furandicarboxylate-Based Polyesters: Properties and Applications

Miah,

Dong,

Wang

et al. 2024

ACS Sustainable Chem. Eng.

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Polyesters based on 2,5-furandicarboxylic acid (2,5-FDCA) have attracted attention from both academia and industry as a new class of biobased polymers for the growing era of plastics. 2,5-FDCA-based polyesters are 100% renewable, and they are an alternative to petroleum-based or terephthalic acid (TPA)-based polyesters. Moreover, scientists and plastics experts have recognized bioplastics as an eco-friendly solution to developing cost-effective renewable plastics. The growth of the bioplastics market depends on a sustainable economy, population growth, and rapid changes in different polymers. Although a variety of auxiliaries have been practically used in recent years, the production of bioplastics from 2,5-FDCA monomers by oxidation of 5-hydroxymethylfurfural (HMF) is a relatively innovative field of research. This review focuses on the properties and applications of 2,5-FDCA-based polyesters in the packaging and coating industries for producing biobased postconsumer products. The manufacturability, excellent (thermal, mechanical, and barrier) features, and applications in various fields of available 2,5-FDCAbased homo-and copolyesters are discussed. Biobased 2,5-FDCA pure homo-and copolyesters have recently progressed with exceptional properties for their counterparts petroleum-based polyesters. In particular, the mechanical performance of 2,5-FDCAbased pure homopolyesters such as poly(ethylene 2,5-furandicarboxylate) (PEF) and poly(propylene 2,5-furandicarboxylate) (PPF) has the highest tensile strength (σ b ) values of 84.07 ± 4.43 and 90 ± 6 MPa, respectively, compared with other homopolyesters. On the other hand, 2,5-FDCA-based neat copolyesters like poly(ethylene 2,5-thiophenedicarboxylate) (PETF) and poly(ethylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) (PECF) had maximum tensile strength (σ b ) values of 97−98 and 59−75 MPa, respectively, compared to other copolyesters. In addition, we also compared and observed the highest Young's modulus (E) values of pure PEF (5248 ± 328 MPa) and pure PPF (2460 ± 280 MPa) homopolyesters and of neat PETF (3100−3300 MPa) and neat PECF (1740−2300 MPa) copolyesters. Furthermore, the elongation at break (ε b ) values of pure poly(decylene furandicarboxylate) (PDF) (986 ± 82%) and pure poly(butylene 2,5-furandicarboxylate) (PBF) (368 ± 43%) homopolyesters and neat poly(pentylene furandicarboxylate) (PPeF) (1050 ± 200%) and neat poly(1,4-butanediol 2,5-thiophenedicarboxylate) (PBTF) (900 ± 84%) copolyesters had the highest values compared to other pure homo-and copolyesters. Finally, the results of the barrier improvement factor (BIFp) study showed that neat PPeF copolyesters had the highest values of O 2 (227 BIFp) and CO 2 (979 BIFp) compared to other pure homo-and copolyesters.

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“…In recent years, due to the rise of oil prices and the decline of crude oil reserves, the use of biomass materials to modify PF has become one of the focuses of polymer application development. Such as lignin [15] , cardanol [16] , tannin [17] , plant pyrolysis oil [18] , eugenol [19] , vanillic acid [20] and cellulose [21] etc., have made some progresses in the biological modi cation research. These raw materials are environmentally friendly and renewable and can play a very important role in the face of the oil and energy crises.…”

Section: Introductionmentioning

confidence: 99%

A Novel Bio-Mass Resveratrol-Modified Lignin-Based Phenolic Resin with High Glass Transition Temperature and Improved Mechanical Properties

Zhang,

Meng,

et al. 2024

J Polym Environ

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The preparation of green bio-based phenolic resin with high performance has far-reaching signi cance for sustainable development and is an important research direction for researchers in recent years. In this study, a novel resveratrol-modi ed lignin-based phenolic phenolic resin (R-LPF) with ultra-high T g and improved mechanical properties was synthesized with biomass phenol of resveratrol and lignin as raw materials. The curing behaviors of phenolic resin (PF), lignin phenolic resin (LPF) and R-LPF were investigated. The thermal mechanical properties, thermal stability, comprehensive mechanical properties, frictional properties and morphology were systematically tested and analyzed. The results show that the highest T g of the modi ed R-LPF reaches 346.2°C, which is much higher than that of traditional PF, and the thermal and mechanical properties of the novel R-LPF are also signi cantly improved. The T s reaches 231.5°C, and the residual carbon rate reaches 66.2% at 800°C. The improved tensile strength, bending strength and impact strength are 28.72 ± 1.10 MPa, 57.58 ± 1.95 MPa and 3.14 ± 0.19 MPa, respectively. Compared with PF and LPF, the wear resistance is also signi cantly improved. Due to the rigid structure and high crosslinking density, the modi ed resin has excellent properties and provides broad application prospects in resin-based friction materials for the bioresource of resveratrol.

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Eugenol: extraction, properties and its applications on incorporation with polymers and resins—a review

Cited by 15 publications

References 168 publications

Eugenol-Based Polymeric Materials—Antibacterial Activity and Applications

Eugenol-Based Polymeric Materials—Antibacterial Activity and Applications

Recent Progress on Sustainable 2,5-Furandicarboxylate-Based Polyesters: Properties and Applications

A Novel Bio-Mass Resveratrol-Modified Lignin-Based Phenolic Resin with High Glass Transition Temperature and Improved Mechanical Properties

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