2024
DOI: 10.52326/jes.utm.2024.31(2).03
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Eu3+ AS A LUMINESCENT PROBE FOR LOCAL SITE SYMMETRY IN Eu(III) COORDINATION COMPOUNDS

Vladislav Ghenea,
Ion Culeac,
Artur Buzdugan

Abstract: The paper deals with the use of tripositive ion Eu3+ as a luminescent probe for the evaluation of the local site symmetry in coordination compounds with europium(III) content. The energy levels of the Eu3+ multiplets in the ligand matrix may be split by the crystal field into a maximum number of 2J+1 components, depending on the site symmetry of the Eu3+ ion. Analysis of photoluminescence spectra provides information on the local site symmetry of the compound. The topic is discussed with reference to literatur… Show more

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