The high-pressure behaviour of LiGdF 4 scheelite (I 4 1 /a, Z = 4) was studied by measuring its angle-dispersive x-ray powder diffraction patterns as a function of pressure and temperature in a diamond anvil cell and a large-volume Paris-Edinburgh cell using a synchrotron radiation source. Upon compression to about 11 GPa at room temperature, the stable structure is of the scheelite type. At higher pressures and T = 298 K, new reflections occur that cannot be explained with the fergusonite structural model previously observed for LiYF 4 . Associated with this is the growth of an amorphous component. All the transformations are largely irreversible upon decompression. Annealing of the sample at 13.1 GPa led to a nucleation of a solid solution series Li y Gd 1−y F 3−2y (P6 3 /mmc, Z = 2) and traces of LiF. The new material Li y Gd 1−y F 3−2y (P6 3 /mmc, Z = 2) was recovered to ambient conditions but back-transformed to a YF 3 -type phase (Pnma, Z = 4) after regrinding at room temperature for several hours. These observations are discussed in relation to the high-pressure high-temperature systematics of the AMX 4 -type compounds.