Estimation of Mineral Accessible Surface Area from Mineral Abundance and Clay Content

Abstract

The mineral reactive surface area is often quantified through a wide range of approaches (e.g., Brunauer−Emmett− Teller adsorption, geometry approximation, and imaging techniques). As such, values vary 1−5 orders of magnitude which can result in large discrepancies when used in reactive transport models to simulate geochemical reaction rates. Simulations carried out using mineral accessible surface areas (ASAs) determined from a coupled 2D and 3D imaging approach have shown better match with reaction rates measured in core-flood experiments. However, such image processing requires large amounts of time and resources. In this work, the possibility of estimating mineral ASAs from easily measured properties like mineral abundance and porosity is explored. Six sandstone samples of varying compositions were studied along with data from three additional samples from the previous literature. Mineral ASAs were quantified using a combined 2D scanning electron microscopy and 3D X-ray nano-computed tomography imaging approach. Sample properties like mineral accessibility, mineral ASAs, connected porosity, and clay content were compared to explore potential correlations between properties. Overall, it was observed that mineral accessibility can be predicted where feldspar mineral accessibility generally increases with increasing abundance and quartz accessibility decreases with increasing clay content. Mineral ASAs vary between samples, depending on the relative abundance of minerals and overall pore connectivity. While the ASA of quartz decreases with abundance, albite and carbonate mineral ASAs increase with abundance. Quantitative observations, including predictive relationships for ASAs from porosity and mineral volume fraction, are developed. Estimations of ASAs and mineral accessibility from more easily quantifiable properties can largely reduce the required extent of image analysis.

Effect of X‐Ray Computed Tomography Imaging Parameters on Quantification of Petrophysical Properties

“…Clay minerals have nanosize pore networks (Beckingham et al., 2017; Gaboreau et al., 2016) which make it challenging to image using laboratory X‐ray micro‐CT instruments. Clay minerals have been noted to also impact the accessibility of other minerals as they are often present as mineral coatings (Qin et al., 2023).…”

Evolution of Mineral-Accessible Surface Area Induced by Geochemical Reactions

“…Recent work noted that accessible mineral surface area, which reflects the proportion of mineral surfaces in contact with reactive fluids, may better reflect the mineral reactive surface area in consolidated porous media. , These accessible mineral surface areas can be quantified using a multiscaling imaging approach. ,,− This surface area was able to better reflect mineral dissolution rates in a consolidated volcanogenic sandstone sample as compared with other commonly used approaches that estimate reactive surface area based on spherical grains with largely arbitrary corrections for surface roughness and reactivity …”