Estimating the Bias of Model Compounds for the Determination of Species-Specific Protonation Constants
Tamás Pálla,
Zsolt Kolompár,
Károly Mazák
et al.
Abstract:The previously unknown
extent of the goodness of using model compounds
for the microspeciation of polyprotic systems was studied. Mirror-symmetric
dibasic compounds and their monosubstituted derivatives were investigated
to quantify how the derivatives are appropriate models of the minor
microspecies to be mimicked in various microspeciation systems. The
results were analyzed using statistical methods. It was found that
the respective O-methyl and S-methyl derivatives of phenols and thiols
as well as the methy… Show more
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