We provide an account of some of the mathematics of Bott periodicity and the Atiyah, Bott, Shapiro construction. We apply these ideas to understanding the twisted bundles of electron bands that underly the properties of topological insulators, spin Hall systems, and other topologically interesting materials. 74.20.Rp, 74.45.+c, 72.25.Dc Now introduce J 5 and construct M = J 1 J 4 J 5 which has M 2 = I and commutes with K and J 1 . M therefore acts within the V + (or V − ) eigenspace of K and divides it into two mutually DIII ≡ O(16r)/U(8r): The m ∈ m 0 's are real skew symmetric matrices that anticommute with J 1 . We can keep C = ϕ as a particle-hole symmetry and take T = ϕ ⊗ J 1 as a time reversal that commutes with H = −iσ 2 ⊗ M and squares to −I. The product of C and T is J 1 , and this a linear (commutes with −iσ 2 ⊗ I) "P " type symmetry that anticommutes with H. AII≡ U(8r)/Sp(4r): The generators m ∈ m 1 are real skew matrices that commute with J 1 and anticommute with J 2 . They can be regarded as skew-quaternion-hermitian matrices with complex entries. We no longer need set i → −iσ 2 ⊗ I as the matrices no longer have elements coupling between the artificial copies. We instead use J 1 as the surrogate for "i." Now H = J 1 m is real symmetric, and commutes with T = J 2 . This T acts as a time reversal operator squaring to −I. CII≡ Sp(4r)/Sp(2r) × Sp(2r): The matrices m ∈ m 2 commute with J 1 and J 2 but anticommute with J 3 . Again H = J 1 m. We can set T = J 3 as this commutes with with H and squares to −I. P = J 2 J 3 anticommutes with H but commutes with J 1 (and so is a linear map) while C = J 2 anticommutes with H, is antilinear and squares to −I. C≡ {Sp(2r) × Sp(2r)}/Sp(2r) ≃ Sp(2r): The matrices m ∈ m 3 commute with J 1 , J 2 , J 3 , and anticommute with J 4 , and we can restrict ourselves to the subspace in which K = J 1 J 2 J 3 takes a definite value, say +1. The Hamiltonian J 1 m commutes with J 4 -but 15 J 4 does not commute with J 1 J 2 J 3 and so is not allowed as an operator on our subspace.Indeed no product involving J 4 is allowed. But C = J 2 commutes with J 1 J 2 J 3 and still anticommutes with H. Thus we still have a particle-hole symmetry squaring to −1.The old time reversal J 3 now anticommutes with H and looks like another particlehole symmetry, but is not really an independent one as in this subspace J 3 = J 2 J 1 and J 1 is simply multiplication by "i." CI≡ Sp(2r)/U(2r): The m ∈ m 4 anticommute with J 5 . Now J 4 J 5 commutes with J 1 J 2 J 3 , and so is an allowed operator. It anticommutes with H = J 1 m and commutes with J 1 .It is therefore a "P "-type linear map. The map T = J 2 J 4 J 5 is antilinear (anticommutes with J 1 ), commutes with H and T 2 = +I. We can take C = J 2 again. AI ≡ U(2r)/O(2r): The m ∈ m 5 n anticommute with J 6 , and we are to restrict ourselves to the subspace on which K = J 1 J 2 J 3 = +1 and M = J 1 J 4 J 5 = +1. The map T = J 3 J 4 J 6 commutes with K and M and commutes H = J 1 m. We have T 2 = +I.We could equivalently take T = J 2 J 4 J 6 .The m ∈ ...