1992
DOI: 10.1063/1.351406
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Erratum: Subdomain zinc ferrite particles: Synthesis and characterization [J. Appl. Phys. 67, 5509 (1990)]

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“…In the case of the nanoparticles, the situation is more complicated and confused because of the inversion of the cation distribution, size effects, and nonstoichiometry. If the noninverted stoichiometric nanoparticles have an antiferromagnetic ground state (T N ) 13 K) 25 like the bulk material, the ground state of nanosized inverted zinc ferrites is magnetic with a large magnetization which is generally explained by the distribution of the cations. [3][4][5]7,8,[11][12][13][14][15][16][17]20,23 Indeed, in the partially inverted stoichiometric spinel, some Zn 2+ ions occupy B-sites while some Fe 3+ ions are in the tetrahedral ones leading to a magnetically active A sublattice which strongly interacts with the B sublattice.…”
Section: Introductionmentioning
confidence: 99%
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“…In the case of the nanoparticles, the situation is more complicated and confused because of the inversion of the cation distribution, size effects, and nonstoichiometry. If the noninverted stoichiometric nanoparticles have an antiferromagnetic ground state (T N ) 13 K) 25 like the bulk material, the ground state of nanosized inverted zinc ferrites is magnetic with a large magnetization which is generally explained by the distribution of the cations. [3][4][5]7,8,[11][12][13][14][15][16][17]20,23 Indeed, in the partially inverted stoichiometric spinel, some Zn 2+ ions occupy B-sites while some Fe 3+ ions are in the tetrahedral ones leading to a magnetically active A sublattice which strongly interacts with the B sublattice.…”
Section: Introductionmentioning
confidence: 99%
“…Values of δ ranging from 0.03 to 0.6 are reported in the literature, depending strongly upon the preparation procedures. 3,[12][13][14][15][16] ZnFe 2 O 4 nanoparticles have been synthesized with a large variety of methods: coprecipitation, 4,17,[19][20][21]23,26,27,33 microemulsion, 5,18 supercritical sol-gel processing, [12][13][14][15][16] hydrothermal synthesis, 10,25 or high-energy ball milling. 3,[7][8][9]11 The magnetization has been found to increase with grain size reduction.…”
Section: Introductionmentioning
confidence: 99%
“…Nanoscale ferrites of binary transition metals such as Zn-Ni, Zn-Mn, etc., have been reported as catalysts for alkylation of aromatics, used commercially as base material for drugs and chemicals [9,[16][17][18]. Owing to superior magnetic properties of Zn-Mn-and Ni-Zn-based spinel nanoferrites, they are potential material for magnetic cores of read-write head for recording [19]. Banerjee et al [9] have reported on catalytic performance of nanocrystalline Zn-Cu ferrite (ZCFO) for alkylation of pyridine.…”
Section: Introductionmentioning
confidence: 99%