1994
DOI: 10.1063/1.468520
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Erratum: State-to-state rotational energy transfer measurements in methane (CHD3) by infrared double resonance with a tunable diode laser [J. Chem. Phys. 100, 5519 (1994)]

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Cited by 11 publications
(24 citation statements)
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“…Beyond state-to-state experiments [41][42][43] averaged quantities such as the average energy transferred in a collision (< DE > ) have been measured in cases where the density of states of the highly excited molecules was too large for state specific probing of quantum states. [44,45] Recently, it has been shown that the technique of kinetically controlled selective ionisation (KCSI) developed by Luther et al [46] can provide moments of energy transfer (< DE > , < DE 2 > ), as well as energy transfer transition probabilities PA C H T U N G T R E N N U N G (E',E) for highly excited molecules [47,48] at high densities of states.…”
Section: Molecular Collisional Energy Transfer At Low Temperaturesmentioning
confidence: 99%
“…Beyond state-to-state experiments [41][42][43] averaged quantities such as the average energy transferred in a collision (< DE > ) have been measured in cases where the density of states of the highly excited molecules was too large for state specific probing of quantum states. [44,45] Recently, it has been shown that the technique of kinetically controlled selective ionisation (KCSI) developed by Luther et al [46] can provide moments of energy transfer (< DE > , < DE 2 > ), as well as energy transfer transition probabilities PA C H T U N G T R E N N U N G (E',E) for highly excited molecules [47,48] at high densities of states.…”
Section: Molecular Collisional Energy Transfer At Low Temperaturesmentioning
confidence: 99%
“…28 In these experiments a particular CO rotational state in vϭ2 is prepared by ͑2-0͒ overtone band absorption of a ''pump'' photon, and the subsequent collision induced populations in other rotational levels of vϭ2 are a͒ Author to whom correspondence should be addressed. Electronic mail: gordon.hager@kirtland.af.mil determined by absorption of a ''probe'' photon in the ͑3-2͒ band.…”
Section: Introductionmentioning
confidence: 99%
“…Indeed, in studies of energy transfer in the intrinsically symmetric top CHD3, Klaassen et al [23] have observed the expected propensities for Ak = 0, 3, with the final state selectivity predicted from the symmetry of the molecule. Intriguingly, then, energy transfer in a spherical top such as methane or silane reflects the internal structure of the target molecule, and is quite independent from details of the short-range forces that might be expected to govern rotational energy transfer.…”
Section: Energy Transfer Within Vibrationally Excited Polyatomic Molementioning
confidence: 94%