The negatively-charged silicon-vacancy (SiV − ) color center in diamond has recently emerged as a promising system for quantum photonics. Its symmetry-protected optical transitions enable creation of indistinguishable emitter arrays and deterministic coupling to nanophotonic devices. Despite this, the longest coherence time associated with its electronic spin achieved to date (∼ 250 ns) has been limited by coupling to acoustic phonons. We demonstrate coherent control and suppression of phonon-induced dephasing of the SiV − electronic spin coherence by five orders of magnitude by operating at temperatures below 500 mK. By aligning the magnetic field along the SiV − symmetry axis, we demonstrate spin-conserving optical transitions and single-shot readout of the SiV − spin with 89% fidelity. Coherent control of the SiV − spin with microwave fields is used to demonstrate a spin coherence time T2 of 13 ms and a spin relaxation time T1 exceeding 1 s at 100 mK. These results establish the SiV − as a promising solid-state candidate for the realization of quantum networks.Quantum networks require the ability to store quantum information in long-lived memories, to efficiently interface these memories with optical photons and to provide quantum nonlinearities required for deterministic quantum gate operations [1,2]. Even though key building blocks of quantum networks have been demonstrated in various systems [3,4], no solid-state platform has satisfied these requirements. Over the past decade, solid-state quantum emitters with stable spin degrees of freedom such as charged quantum dots and nitrogenvacancy (NV) centers in diamond have been investigated for the realization of quantum network nodes [5]. While quantum dots can be deterministically interfaced with optical photons [6], their quantum memory time is limited to the µs scale [7] due to interactions with their surrounding nuclear spin bath. In contrast, NV centers have an exceptionally long-lived quantum memory [8] but suffer from weak, spectrally unstable optical transitions [9]. Despite impressive proof-of-concept experimental demonstrations with these systems [10,11], scaling to a large number of nodes is limited by the challenge of identifying suitable quantum emitters with the combination of strong, homogeneous and coherent optical transitions and long-lived quantum memories.The negatively-charged silicon-vacancy (SiV − ) has recently been shown to have bright, narrowband optical transitions with a small inhomogeneous broadening [12,13]. The optical coherence of the SiV − is protected by its inversion symmetry [14], even in nanostructures [15]. These optical properties were recently used to show strong interactions between single photons and single SiV − centers and to probabilistically entangle two SiV − centers in a single nanophotonic device [16]. At 4 K, however, the SiV − spin coherence is limited to ∼ 100 ns due to coupling to the phonon bath, mediated by the spin-orbit interaction [17][18][19][20][21].In this Letter, we demonstrate high-fidelity coherent ...