2019
DOI: 10.1021/acs.jced.8b00961
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Equilibrium Adsorption Isotherms for H2O on Zeolite 13X

Abstract: Adsorption isotherms are reported for pure water vapor on zeolite 13X (also called zeolite NaX) pellets. Data were obtained using a gravimetric method over a temperature range of 25 to 100 °C and a pressure range of 0.006 to 25 kPa. These pure-component equilibria are fit with the Sips, Toth, and multisite Langmuir models, all modified with the Aranovich–Donohue (A–D) model. The A–D Sips isotherm is recommended for modeling water adsorption on zeolite 13X because it provides the best agreement with the measure… Show more

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Cited by 26 publications
(12 citation statements)
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“…A consequence of the lower SAR and subsequent cation density in the zeolite was the observed affinity and range of heats of adsorption toward water in the Na-SSZ-13 sample studied here. The adsorption isotherm of water at low partial pressures revealed less uptake and affinity compared to other aluminosilicate zeolites. , …”
Section: Resultsmentioning
confidence: 91%
“…A consequence of the lower SAR and subsequent cation density in the zeolite was the observed affinity and range of heats of adsorption toward water in the Na-SSZ-13 sample studied here. The adsorption isotherm of water at low partial pressures revealed less uptake and affinity compared to other aluminosilicate zeolites. , …”
Section: Resultsmentioning
confidence: 91%
“…Its performance is on par with zeolite 13X over all factors considered here. Considering its water co-adsorption and regeneration characteristics are more desirable than zeolite 13X, [67][68][69] it may be a preferred candidate assuming that long-term cyclic stability can be verified. It is possible that the MOFs investigated here display better performance in a TSA process.…”
Section: Comparison Of Performance and Cost With Respect To Targets -mentioning
confidence: 99%
“…Furthermore, the Langmuir adsorption kinetic model was also used to fit the experimental data from the batch test because, unlike the saturation-growth-rate model, the Langmuir model can cluster different batch assays. The Langmuir model has previously been used to evaluate the adsorption process onto different materials [49][50][51]:…”
Section: Adsorption Modellingmentioning
confidence: 99%