Equilibria in Partially Miscible Liquids.

Antonoff, George; Chanin, Milton; Hecht, Morris

doi:10.1021/j150418a008

Cited by 9 publications

(5 citation statements)

References 1 publication

(1 reference statement)

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“…In this case, Eq. ( 1 ) is reduced to σ LS = σ S − σ L , known as the Antonoff law 22 , which has been widely applied to estimate internal energy between immiscible liquids. Values for the solid UO 2 surface energy and liquid CsI surface energy values obtained from the literature 17 , 23 were used in this calculation.…”

Section: Resultsmentioning

confidence: 99%

High wettability of liquid caesium iodine with solid uranium dioxide

Kurosaki

Suzuki

Uno

et al. 2017

Sci Rep

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In March 2011, the Fukushima Daiichi Nuclear Power Plant accident caused nuclear fuel to melt and the release of high-volatility fission products into the environment. Caesium and iodine caused environmental contamination and public exposure. Certain fission-product behaviours remain unclear. We found experimentally that liquid CsI disperses extremely favourably toward solid UO2, exhibiting a contact angle approaching zero. We further observed the presence of CsI several tens of micrometres below the surface of the solid UO2 sample, which would be caused by the infiltration of pores network by liquid CsI. Thus, volatile fission products released from molten nuclear fuels with complex internal composition and external structure migrate or evaporate to varying extents, depending on the nature of the solid–liquid interface and the fuel material surface, which becomes the pathway for the released fission products. Introducing the concept of the wettability of liquid chemical species of fission products in contact with solid fuels enabled developing accurate behavioural assessments of volatile fission products released by nuclear fuel.

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Section: Resultsmentioning

confidence: 99%

High wettability of liquid caesium iodine with solid uranium dioxide

Kurosaki

Suzuki

Uno

et al. 2017

Sci Rep

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“…Previous investigations carried out in this laboratory dealing with the effect of added strong electrolytes on the solubility of silver acetate in water and in mixed solvents may be classified in two groups: (J) those in which the added electrolyte contained no ion common to those supplied by the silver acetate (5, 8, 9, 10); (2) those in which the added electrolyte furnished either silver ion or acetate ion (6, 7). For our present purpose, the results obtained in the investigations of the first group may be summarized in the statement that the effect of the added electrolytes on the solubility of silver acetate could be accounted for, with a considerable degree of accuracy, in solutions of low and moderately high ionic…”

Section: Introductionmentioning

confidence: 99%

“…tively, and 7I0 is the interfacial tension, all quantities, as well as WA and W'c (cf. later), referring to mutually saturated phases and surfaces) is always zero, according to Antonoff (2,3). A number of other investigators, however, have found small negative values in the case of many amphipathic organic compounds.…”

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confidence: 95%

The Equilibrium Spreading Coefficient of Amphipathic Organic Liquids on Water

Heymann¹,

Yoffe²

1945

J. Phys. Chem.

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“…This paper is restricted to measurements of density as a function of temperature, and the material chosen is propyl alcohol. This alcohol is miscible with water in all proportions and therefore it is impossible to apply the method of investigation used for the partially soluble liquids (2) such as isoamyl alcohol. There it was shown that with this alcohol, if it is chemically pure, the difference in properties due to previous history is enormous.…”

Section: Introductionmentioning

confidence: 99%

“…Received December 15, 191,3 Some years ago, following a study (3) of the system aniline-acetic acid in which it was found that two compounds were formed, one of them metastable throughout the entire range, O'Connor (4) carried out a similar investigation with acetic acid and the homologues of aniline. The systems studied were the o-, m-, and p-toluidines, mesidine, and dimethvlaniline, each with acetic acid, and conclusions were drawn relating the nature of the compounds formed to the structure of the primary aromatic amines.…”

mentioning

confidence: 99%