Ullmann's Encyclopedia of Industrial Chemistry 2000
DOI: 10.1002/14356007.a09_531
|View full text |Cite
|
Sign up to set email alerts
|

Epoxides

Abstract: The article contains sections titled: 1. Introduction 2. Reactions of Epoxides … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

2
64
0
1

Year Published

2003
2003
2022
2022

Publication Types

Select...
6
3

Relationship

0
9

Authors

Journals

citations
Cited by 72 publications
(68 citation statements)
references
References 74 publications
2
64
0
1
Order By: Relevance
“…The bond angels of an epoxide deviate from the tetrahedral angel of other sp 3 -hybridized ether-carbon atoms, leading to so-called bent bonds. This result in a high amount of ring-strain in epoxides which accounts for the high chemical reactivity of epoxides [43]. A nucleophilic addition of H 2 O at C10, catalyzed by a hydrolase, results in the opening of the 16,17 S -PD n-3 DPA epoxide, culminating in the formation of PD1 n-3 DPA .…”
Section: Resultsmentioning
confidence: 99%
“…The bond angels of an epoxide deviate from the tetrahedral angel of other sp 3 -hybridized ether-carbon atoms, leading to so-called bent bonds. This result in a high amount of ring-strain in epoxides which accounts for the high chemical reactivity of epoxides [43]. A nucleophilic addition of H 2 O at C10, catalyzed by a hydrolase, results in the opening of the 16,17 S -PD n-3 DPA epoxide, culminating in the formation of PD1 n-3 DPA .…”
Section: Resultsmentioning
confidence: 99%
“…It starts with glycidol that can be economically prepared by the epoxidation of allyl alcohol [30]. The alkynediol 2 was prepared from glycidol by using a four-step sequence reported by Pattenden and co-workers [31].…”
Section: Resultsmentioning
confidence: 99%
“…[52] The epoxidation is therefore one of the most important oxidation reactions in organic synthesis resulting in a high interest in the immobilization of enantioselective epoxidation catalysts. [53] In 1998, Abbenhuis et al reported the immobilization of the titanium(IV)-silsesquioxane complex 13 known as an active and durably epoxidation catalyst in solution.…”
Section: Epoxidation Reactionsmentioning
confidence: 99%