Epoxidação do óleo de soja com o sistema catalítico [MoO2(acac)2]/TBHP EM [bmim][PF6]

Abstract:The catalytic properties of niobium(V) oxide (Nb 2 O 5 -CBMN) of different grades: amorphous, optical and ultra-pure, untreated or heat-treated at 400, 500, 700 and 900 • C were studied, before and after interaction with H 2 O 2 , by in situ Raman, FTIR-ATR and diffuse reflectance UV-Visible spectroscopy. The presence of different reaction sites for NbO 7 and NbO 8 type systems, which are directly related to surface defects present in different states of crystallization, were fully characterized. The reactivity of different catalysts obtained from niobium(V) oxide was investigated, using the oxidation of methyl linoleate in the presence of hydrogen peroxide as probe reaction. The reaction was followed by GC-MS, as well as by 1 H and 13 C NMR spectrometry and the dominant product was 9-oxo-nonanoic acid methyl ester. A reaction mechanism related to an auto-oxidation process must be occurring, leading initially to the formation of hydroperoxides, which decompose rapidly via Hock-type rearrangement, leading to the formation of aldehydes.

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New Insights on the Oxidation of Unsaturated Fatty Acid Methyl Esters Catalyzed by Niobium(V) Oxide. A Study of the Catalyst Surface Reactivity

Cecchi

Cesarín-Sobrinho

Ferreira

et al. 2018

Catalysts

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Epoxidação do óleo de soja com o sistema catalítico [MoO2(acac)2]/TBHP EM [bmim][PF6]

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New Insights on the Oxidation of Unsaturated Fatty Acid Methyl Esters Catalyzed by Niobium(V) Oxide. A Study of the Catalyst Surface Reactivity

New Insights on the Oxidation of Unsaturated Fatty Acid Methyl Esters Catalyzed by Niobium(V) Oxide. A Study of the Catalyst Surface Reactivity

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