Epitaxial LnNiO3 (Ln=La, Pr, Nd, Sm) films from 4f–3d heterometallic complexes

Perovskite LaNiO 3 is of immense significance in a range of fields such as heterogeneous catalysis. Herein, new convenient approach for preparing LaNiO 3 via thermolysis of new simple complexes, [Ni (bpyis 1,10-phenanthroline), is reported. These first examples of unambiguously characterized LaNiO 3 precursors are chemically stable and can be synthesized rapidly in good yields. While virtually monophasic LaNiO 3 can be prepared from 2 via only 3-h annealing on air at 800 C, there are always minor admixtures in oxide samples prepared from 1. Peculiarities of intrinsic thermal transformations of 1 and 2 affecting such difference have been revealed. Thus,

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New simple La‐Ni complexes as efficient precursors for functional LaNiO₃‐based ceramics

Гавриков

Belova

Yapryntsev

et al. 2021

Applied Organom Chemis

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Discrepancies in the morphology and physical properties of amorphous and crystalline sprayed lanthanum nickel oxide films

2013

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Interaction of nickel aminoalkoxide with samarium β-diketonate – Identification of new precursors for MOCVD synthesis of SmNiO3 perovskite films

2013

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Epitaxial LnNiO3 (Ln=La, Pr, Nd, Sm) films from 4f–3d heterometallic complexes

Cited by 3 publications

References 25 publications

New simple La‐Ni complexes as efficient precursors for functional LaNiO₃‐based ceramics

New simple La‐Ni complexes as efficient precursors for functional LaNiO₃‐based ceramics

Discrepancies in the morphology and physical properties of amorphous and crystalline sprayed lanthanum nickel oxide films

Interaction of nickel aminoalkoxide with samarium β-diketonate – Identification of new precursors for MOCVD synthesis of SmNiO3 perovskite films

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Epitaxial LnNiO3 (Ln=La, Pr, Nd, Sm) films from 4f–3d heterometallic complexes

Cited by 3 publications

References 25 publications

New simple La‐Ni complexes as efficient precursors for functional LaNiO3‐based ceramics

New simple La‐Ni complexes as efficient precursors for functional LaNiO3‐based ceramics

Discrepancies in the morphology and physical properties of amorphous and crystalline sprayed lanthanum nickel oxide films

Interaction of nickel aminoalkoxide with samarium β-diketonate – Identification of new precursors for MOCVD synthesis of SmNiO3 perovskite films

Contact Info

Product

Resources

About

New simple La‐Ni complexes as efficient precursors for functional LaNiO₃‐based ceramics

New simple La‐Ni complexes as efficient precursors for functional LaNiO₃‐based ceramics