2000
DOI: 10.1016/s0308-8146(00)00099-6
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Epimerisation of catechins in green tea infusions

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Cited by 187 publications
(143 citation statements)
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“…It was also found that the concentration of catechin increased at a higher rate when the RH was elevated, probably due to limited access of oxygen to roasted material. This assumption agrees with observations of Wang and Helliwell [29] who noticed that at high temperature, in particular under anaerobic conditions, more catechins, being (−) epiforms (2R, 3R), could undergo conversion to suitable (−) forms (2S, 3R). Similar conclusions were reported by Tamrin et al [18] who reported that during cocoa powder roasting with vacuum (45.6 and 60.8 cmHg) at temperatures from 100 to 120 °C, the low oxygen in the roasting space may slow the oxidation processes of the catechins.…”
Section: Resultssupporting
confidence: 93%
“…It was also found that the concentration of catechin increased at a higher rate when the RH was elevated, probably due to limited access of oxygen to roasted material. This assumption agrees with observations of Wang and Helliwell [29] who noticed that at high temperature, in particular under anaerobic conditions, more catechins, being (−) epiforms (2R, 3R), could undergo conversion to suitable (−) forms (2S, 3R). Similar conclusions were reported by Tamrin et al [18] who reported that during cocoa powder roasting with vacuum (45.6 and 60.8 cmHg) at temperatures from 100 to 120 °C, the low oxygen in the roasting space may slow the oxidation processes of the catechins.…”
Section: Resultssupporting
confidence: 93%
“…The effect of water type on the ECG content was in agreement with the trend observed with EGCG, EGC and EC, but the differences were not significant (p [ 0.05). In general, the catechin content was the highest in tea infusions made with pure water, intermediate with spring water, and the lowest with tap water, consistent with a previous report that catechins were more easily epimerised and then rapidly degraded in infusions prepared with tap water, compared with purified water (Wang and Helliwell 2000), and also with the observation that green tea extracts prepared with tap water contained less polyphenols (Zhou et al 2009). This could be explained by the complexity of ions in tap water including Ca 2?…”
Section: Effect Of Water Quality On Individual Catechin Contentsupporting
confidence: 89%
“…, K ? , or by differences in pH between tap and purified water (Wang and Helliwell 2000). Ions such as Ca 2?…”
Section: Effect Of Water Quality On Individual Catechin Contentmentioning
confidence: 99%
“…These results indicate that excessive extraction temperatures above 801C could lead to an increased epimerization of the epistructured catechins to non-epistructured catechins. This has also been observed in previous studies [16,17], which found that epimerisation from the epistructured to the non-epistructured catechins happened predominantly when the brewing temperature was above 801C. Therefore, care should be taken to prevent exposure of the catechins to temperatures above 801C during hot water extractions.…”
Section: Effect Of Extraction Temperaturesupporting
confidence: 82%