Enzymatic and Chemo–catalytic Redox Deracemization: Recent Progress
Qian Wan,
Zehua Wang,
Huairi Sun
et al.
Abstract:The precise synthesis of chiral small molecules is a core research area in chemical science. Deracemization, an appealing technology that converts racemate to its single enantiomer with the same constitution in theoretical 100% yield, appears as a straightforward and efficient strategy in asymmetric synthesis. A cascading redox sequence was the most employed approach to drive deracemization through destroy and recreate the stereocenter in a given molecule. This review mainly focuses on the progress of redox der… Show more
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