Environmentally Sustainable Aluminum-Coordinated Poly(tetrahydroxybenzoquinone) as a Promising Cathode for Sodium Ion Batteries

Kim, Hee Joong; Kim, Young‐Jin; Shim, Ji-Yeon; Jung, Ki Hwan; Jung, Min Yang; Kim, Hanseul; Lee, Jong Chan; Lee, Kyu‐Tae

doi:10.1021/acsami.7b13911

Cited by 41 publications

(28 citation statements)

References 79 publications

(117 reference statements)

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“…Almost 100% capacity retention was found after 1024 cycles in SIBs. Kim et al . developed a unique strategy of coordinating polymers with a metal to improve the performance of SIBs.…”

Section: Polymeric Carbonyls Materials (Pcm) For Libs/sibsmentioning

confidence: 99%

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

Amin

Mao

Wei

2018

Macromol. Rapid Commun.

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Advancement in mobile electronics is driving progress in lithium ion batteries. Recently, organic electrode materials have emerged as promising candidates for lithium ion batteries due to their high theoretical capacity, ease of synthesis, versatility of structure, and abundance. Polymerization is a strategy used to overcome the issues associated with small organic molecules for charge storage application. The focus of this review is on the most recent progress in the field of polymeric carbonyl materials for lithium ion batteries (LIBs) and sodium ion batteries (SIBs). Advantages of organic electrode materials, device architecture, and charge storage mechanism are discussed. Challenges associated with carbonyl‐based electrodes and some recent solutions are outlined. Later, a comparison of theoretical capacity, practical capacity, and cyclic life are presented for different carbonyl systems. Capacity‐fading phenomena and structural degradation during charging are discussed where necessary. Some key parameters for the design of flexible batteries are highlighted and an overview of some recent contributions of our group in this field are reported. Finally, some future prospects for researchers in this field are outlined.

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“…Almost 100% capacity retention was found after 1024 cycles in SIBs. Kim et al . developed a unique strategy of coordinating polymers with a metal to improve the performance of SIBs.…”

Section: Polymeric Carbonyls Materials (Pcm) For Libs/sibsmentioning

confidence: 99%

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

Amin

Mao

Wei

2018

Macromol. Rapid Commun.

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“…Sodium‐based batteries are considered promising and are widely explored by many research groups worldwide . Various transition‐metal oxides, polyanionic compounds, ferrocyanides, organic materials, and polymers are considered as possible cathode materials for Na‐ion batteries. In recent years, polyanionic frameworks within the NASICON (Na‐Super‐Ionic‐Conductors) structural family were heavily investigated due to their specific 3D framework structure, stable long‐term cycling ability, and high Na + mobility …”

Section: Introductionmentioning

confidence: 99%

A NASICON‐Type Positive Electrode for Na Batteries with High Energy Density: Na₄MnV(PO₄)₃

et al. 2018

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Among them, Na 3 V 2 (PO 4 ) 3 (NVP) has been identified so far as the most interesting one as it possesses satisfactory energy density and high power for extended cycle life. Its crystal structure can be described as a 3D framework of VO 6 octahedra and PO 4 tetrahedra connected to each other by common corners forming so-called "lantern units" along the c direction of the commonly used hexagonal cell. Sodium cations were described as randomly disordered over two sodium sites (Na(1), 6b and Na(2), 18e) [18] until Chotard et al. discovered that below 280 K, the so called α-NVP form crystallized in a monoclinic superstructure due to a fully ordered distribution of Na +[19] similar to the ordering previously reported in α-Na 3 Ti 2 (PO 4 ) 3 . [51] The synthesis of Na 3 V 2 (PO 4 ) 3 was first reported by Delmas. [20] Gopalakrishnan [21] later on reported on the possible extraction of three Na + toward the novel sodium-free V IV V V (PO 4 ) 3 composition. Afterward, the electrochemical extraction of Na + from Na 3 V 2 (PO 4 ) 3 to NaV 2 (PO 4 ) 3 (with a theoretical capacity of 117.6 mAh g −1 at 3.4 V vs Na/Na) was extensively investigated. [22][23][24][25][26] A large number of special treatments (e.g., carbon coating, particle shape controlling) was also proposed to improve battery performances. [27][28][29][30][31] It is important to note that only 2Na formula unit −1 have been completely removed from the structure during charging up to now. A possible activation of the V 4+/5+ redox couple at higher voltages may also contribute to the increasing of the energy density of NVP-based materials, as demonstrated in a series of works by using a metal substitution of a part of V 3+ in the structure of NVP. In recent years, several elements have been chosen for the partial substitution of V into the crystal structure of this promising material (such as Ni, [32][33][34] Al, [35,36] Fe 3+ , [34,37] Zr 4+ , [38] Mn 3+ , [39] Mn 2+ , [34,40] Cr 3+ , [41][42][43] Ti 4+ , [44][45][46] Mo 6+ , [47] and Mg 2+[48] ).In this work, Mn 2+ was used as a substituting ion to enhance the capacity of the Na 3 V 2 (PO 4 ) 3 cathode material. Inspired by the recent work of Zhou et al., [34] nearly single-phase Na 4 MnV(PO 4 ) 3 (98.5 wt%) powders were synthesized and studied structurally and electrochemically in details. In operando X-ray diffraction (XRD) studies during electrochemical operation show for the first time that Na 4 MnV(PO 4 ) 3 can deliver 156 mAh g −1 toward the new composition NaMnV(PO 4 ) 3 . Results and DiscussionThe crystal structure of Na 4 MnV(PO 4 ) 3 has been fully determined using high-resolution synchrotron powder XRD (SXRD) dataThe mixed Mn 2+ /V 3+ Na-super-ionic-conductor (NASICON) cathode material Na 4 MnV(PO 4 ) 3 is prepared by solid-state reaction at 800 °C under argon. When used as a positive electrode in Na batteries, this material can exchange three electrons for two transition metals, that is, yielding a high gravimetric capacity of 156 mAh g −1 on charge when the upper cutoff voltage is set to 4.3 V...

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“…On the one hand, aromatic carbonyl compounds (ACCs) can be used in both aqueous and organic solution electrolytes in batteries. On the other hand, organic electrode materials are being widely explored for various metal ion batteries, including lithium‐ion batteries (LIBs), sodium‐ion batteries (SIBs), potassium‐ion batteries (KIBs), magnesium‐ion batteries (MIBs), zinc‐ion batteries (ZIBs), aluminum‐ion batteries (AIBs), and calcium‐ion batteries (CIBs) …”

Section: Introductionmentioning

confidence: 99%

Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes

et al. 2019

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To sustainably satisfy the growing demand for energy, organic carbonyl compounds (OCCs) are being widely studied as electrode active materials for batteries owing to their high capacity, flexible structure, low cost, environmental friendliness, renewability, and universal applicability. However, their high solubility in electrolytes, limited active sites, and low conductivity are obstacles in increasing their usage. Here, the nucleophilic addition reaction of aromatic carbonyl compounds (ACCs) is first used to explain the electrochemical behavior of carbonyl compounds during charge–discharge, and the relationship of the molecular structure and electrochemical properties of ACCs are discussed. Strategies for molecular structure modifications to improve the performance of ACCs, i.e., the capacity density, cycle life, rate performance, and voltage of the discharge platform, are also elaborated. ACCs, as electrode active materials in aqueous solutions, will become a future research hotspot. ACCs will inevitably become sustainable green materials for batteries with high capacity density and high power density.

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Environmentally Sustainable Aluminum-Coordinated Poly(tetrahydroxybenzoquinone) as a Promising Cathode for Sodium Ion Batteries

Cited by 41 publications

References 79 publications

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

A NASICON‐Type Positive Electrode for Na Batteries with High Energy Density: Na₄MnV(PO₄)₃

Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes

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Environmentally Sustainable Aluminum-Coordinated Poly(tetrahydroxybenzoquinone) as a Promising Cathode for Sodium Ion Batteries

Cited by 41 publications

References 79 publications

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

Recent Progress in Polymeric Carbonyl‐Based Electrode Materials for Lithium and Sodium Ion Batteries

A NASICON‐Type Positive Electrode for Na Batteries with High Energy Density: Na4MnV(PO4)3

Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes

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A NASICON‐Type Positive Electrode for Na Batteries with High Energy Density: Na₄MnV(PO₄)₃