The influence of the flue gas temperature
on the concentration
of metals in fly ash and deposited ash during heavy-metal-contaminated
woody biomass combustion was investigated. The biomass gathered from
heavy-metal-contaminated soil was combusted in a 34 kWth boiler, and the metal flow was monitored through the metal content
of solid residues for up to 30 elements. The flue gas temperature
was controlled by the heat exchanger, and it was found that, by decreasing
the temperature, more metals can be kept inside the combustion system,
potentially lowering the environmental heavy metal pollution because
more metal volatiles are being condensed on fly ash particles, which
can be separated using known filtration techniques. The concentrations
of Ag, Co, Cr, Cu, Fe, Ga, Mg, Mn, Ni, Pb, Si, Sn, Ti, V, and Zr were
significantly higher in fly ash samples collected at 150 °C flue
gas temperature compared to the 250 °C case, indicating a strong
temperature dependence. A minor temperature dependence was observed
in deposited ash samples for most elements. On the basis of the results,
decreasing the flue gas temperature is a viable method for lowering
metal emission during contaminated woody biomass combustion.