2020
DOI: 10.3390/e22070793
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Entropy and the Second Law of Thermodynamics—The Nonequilibrium Perspective

Abstract: An alternative to the Carnot-Clausius approach for introducing entropy and the second law of thermodynamics is outlined that establishes entropy as a nonequilibrium property from the onset. Five simple observations lead to entropy for nonequilibrium and equilibrium states, and its balance. Thermodynamic temperature is identified, its positivity follows from the stability of the rest state. It is shown that the equations of engineering thermodynamics are valid for the case of local thermodynamic equilibrium, wi… Show more

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Cited by 13 publications
(6 citation statements)
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“…Order, disorder and randomness, all close relatives of entropy, are ambiguous concepts too (Landsman, 2020;Lambert, 2002;Annila and Baverstock, 2016); as one can read in a recent publication, "Order, or disorder, are not well-defined concepts" (Struchtrup, 2020), which echoes the older statement by the mathematician Hans Freudenthal in 1969: "It may be taken for granted that any attempt at defining disorder in a formal way will lead to a contradiction. This does not mean that the notion of disorder is contradictory.…”
Section: The Ambiguous Ordermentioning
confidence: 98%
“…Order, disorder and randomness, all close relatives of entropy, are ambiguous concepts too (Landsman, 2020;Lambert, 2002;Annila and Baverstock, 2016); as one can read in a recent publication, "Order, or disorder, are not well-defined concepts" (Struchtrup, 2020), which echoes the older statement by the mathematician Hans Freudenthal in 1969: "It may be taken for granted that any attempt at defining disorder in a formal way will lead to a contradiction. This does not mean that the notion of disorder is contradictory.…”
Section: The Ambiguous Ordermentioning
confidence: 98%
“…with initial and boundary conditions (2), where x 0 = ε 0 / kT L is the dimensionless energy of particles δ -source, θ(x)=…”
Section: The Second Law In An Open Systemmentioning
confidence: 99%
“…Since the second law considers the transition (relaxation) from a nonequilibrium state to an equilibrium one, it is better to implement the microscopic description by the kinetic theory, the results of which have an explicit time dependence. L. Boltzmann in his famous H -theorem, carried out the first such consideration, which is a microscopic substantiation of the second law for isolated systems [2].…”
Section: Introductionmentioning
confidence: 99%
“…, lo que indica que la energía E al interior del sistema cambia con los ingresos y las salidas, al igual que por transferencia de calor y trabajo que mueve masa a través de los límites; sumado a ello, varias contribuciones al trabajo y a la transferencia de calor, siendo esta . Toda masa que ingresa o sale del sistema carga entropía (un flujo de entropía asociado a un flujo de masa se sintetiza en S =m ṡ, siendo s una media específica de entrada y salida de entropía) y añadiendo términos apropiados para entrada y salida de la segunda ley en los sistemas cerrados se obtiene la segunda ley, el balance de la entropía en los sistemas abiertos: , en donde la entropía S cambia a la entrada y salida del sistema, al igual que a la transferencia de entropía causada por la transferencia de calor y a la generación de entropía ocasionada por procesos irreversibles dentro del sistema (Sgen ≥0), aunque si los procesos dentro del sistema son reversibles, la generación de entropía se desvanece (Sgen=0), sin olvidar que Qk es el calor que cruza el límite del sistema y la temperatura límite es Tk (Struchtrup, 2020).…”
Section: ©Universidad De Caldas 51unclassified