1966
DOI: 10.1002/recl.19660850208
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Enthalpies of solution of some alkali halides in N‐methylformamide at 25°

Abstract: The enthalpies of solution of LiI, NaI, KF, KCl, KBr, KI, RbI and CsI in anhydrous N‐methylformamide (NMF) at concentrations of about 5 × 10−3 molal have been measured with an adiabatic calorimeter. The enthalpies of dilution in NMF were calculated with the aid of the extended Debye‐Hückel theory. The differences in enthalpy of solution of the alkali iodides between (1) water and formamide and (2) water and NMF are compared with the results of van Eck's theory of ionic solvation.

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Cited by 12 publications
(3 citation statements)
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“…In Figure , we plot m s versus anions of the crystallographic radius, r – (the cation is always the same, Na + ). For the three mixtures studied, the solubility decreases with the weight percent of cosolvent, and the order is NaF < NaCl < NaBr < NaI. , …”
Section: Resultsmentioning
confidence: 95%
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“…In Figure , we plot m s versus anions of the crystallographic radius, r – (the cation is always the same, Na + ). For the three mixtures studied, the solubility decreases with the weight percent of cosolvent, and the order is NaF < NaCl < NaBr < NaI. , …”
Section: Resultsmentioning
confidence: 95%
“…The electrolytes studied are practically dissociated in these media, , and the charges of its ions are 1. In Figure , we plot m s versus anions of the crystallographic radius, r – (the cation is always the same, Na + ).…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation