2021
DOI: 10.1002/er.6419
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Entangled spintronic modulated high‐performance Ce 2 O 3 small polaron surface state‐based water splitting cells

Abstract: High-performance spintronic water-splitting devices with high applied power, spintronic population under room temperature have been demonstrated by the Ce 2 O 3 small polaron surface state-based spintronic injection system. Spintronic entanglement tomography decrypts the information about ultrahigh-energy conversion efficiency as high as 140% and the optimal applied voltage 0.682 V.Ce +3 ions demonstrate unpaired d orbital for achieving spin-orbital coupling by accepting the quantum information of angular mome… Show more

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Cited by 9 publications
(2 citation statements)
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“…41 For decades, the polaron theory has been applied not only to study charge transfer but also to explore hydrogen evolution reactions from the surface of materials. 10,19,42 When an excited electron from the internal lattice of a semiconductor is introduced into an ionic lattice of CuO lattice crystal and driven to the material surface with polaron, p-typed polaron accepts the excited electrons and converts them to hydrogens ions for reduction and hydrogen gases evolution; the p-type polaron responds to the hydrogen ions and transfers charge by local polaron surface state as shown in Fig. 5.…”
Section: P-typed Polaronmentioning
confidence: 99%
“…41 For decades, the polaron theory has been applied not only to study charge transfer but also to explore hydrogen evolution reactions from the surface of materials. 10,19,42 When an excited electron from the internal lattice of a semiconductor is introduced into an ionic lattice of CuO lattice crystal and driven to the material surface with polaron, p-typed polaron accepts the excited electrons and converts them to hydrogens ions for reduction and hydrogen gases evolution; the p-type polaron responds to the hydrogen ions and transfers charge by local polaron surface state as shown in Fig. 5.…”
Section: P-typed Polaronmentioning
confidence: 99%
“…Cu 2 O (band gap is only 2.38 eV) has the advantage since the required light source is around 500 nm, which is abundant in the visible light region. From the research of metal oxide semiconductor materials in photoelectrochemical water-splitting reactions, original defects, such as oxygen atoms and ion vacancy-induced polaron surface states, play a critical role in charge transfer and hydrogen-evolution modulation. , In matter physics, the interactions between electrons, atoms, and polarons are well-defined by the basic model of metal ions and oxygen vacancies induced by an interactive redox reaction as a quasiparticle. The affinity among hydrogen ions, oxygen vacancies, and metal ions induced various bonding abilities and further modulated the performance of the hydrogen-reduction reactions for hydrogen gas evolution in water splitting photoelectrochemical processing. From the simulation results of H 2 O on Cu 2 O for photocatalyst and photoelectrochemical reactions, the Cu 2 O nanoparticle with high oxygen vacancies has the highest photocatalytic activity .…”
Section: Introductionmentioning
confidence: 99%