Enriched vacancies of ruthenium doped niobium oxide on hollow graphene sphere as sulfur reduction reaction promoter in lithium sulfur batteries

Chu, Rongrong; Nguyen, Thanh Tuan; Song, Hewei; Bai, Yanqun; Tran, Duy Thanh; Kim, Nam Hoon; Lee, Joong Hee

doi:10.1016/j.apcatb.2024.124030

Applied Catalysis B: Environment and Energy

2024

DOI: 10.1016/j.apcatb.2024.124030

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Enriched vacancies of ruthenium doped niobium oxide on hollow graphene sphere as sulfur reduction reaction promoter in lithium sulfur batteries

Rongrong Chu,

Thanh Tuan Nguyen,

Hewei Song

et al.

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Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Bai,

Nguyen,

Song

et al. 2024

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The high theoretical energy density (2600 Wh kg−1) and low cost of lithium–sulfur batteries (LSBs) make them an ideal alternative for the next‐generation energy storage system. Nevertheless, severe capacity degradation and low sulfur utilization resulting from shuttle effect hinder their commercialization. Herein, Single‐atom Ru‐doped 1T/2H MoS2 with enriched defects decorates V2C MXene (Ru–MoS2/MXene) produced by a new phase‐engineering strategy employed as sulfur host to promote polysulfide adsorption and conversion reaction kinetics. The Ru single atom‐doped adjusts the chemical environment of the MoS2/MXene to anchor polysulfide and acts as an efficient center to motivate the redox reaction. In addition, the rich defects of the MoS2 and ternary boundary among 1T/2H MoS2 and V2C accelerate the charge transfer and ion movements for the reaction. As expected, the Ru–MoS2/MXene/S cathode‐based cell exhibits a high‐rate capability of 684.3 mAh g−1 at 6 C. After 1000 cycles, the Ru–MoS2/MXene/S cell maintains an excellent cycling stability of 696 mAh g−1 at 2 C with a capacity degradation as low as 0.02% per cycle. Despite a high sulfur loading of 9.5 mg cm−2 and a lean electrolyte‐to‐sulfur ratio of 4.3, the cell achieves a high discharge capacity of 726 mAh g−1.

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Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Bai,

Nguyen,

Song

et al. 2024

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View full text Add to dashboard Cite

show abstract

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Enriched vacancies of ruthenium doped niobium oxide on hollow graphene sphere as sulfur reduction reaction promoter in lithium sulfur batteries

Cited by 1 publication

References 58 publications

Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

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Enriched vacancies of ruthenium doped niobium oxide on hollow graphene sphere as sulfur reduction reaction promoter in lithium sulfur batteries

Cited by 1 publication

References 58 publications

Ru Single Atom Dispersed on MoS2/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Ru Single Atom Dispersed on MoS2/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Contact Info

Product

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Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries

Ru Single Atom Dispersed on MoS₂/MXene for Enhanced Sulfur Reduction Reaction in Lithium–Sulfur Batteries