In two-dimensional electron systems confined to GaAs quantum wells, as a function of either tilting the sample in magnetic field or increasing density, we observe multiple transitions of the fractional quantum Hall states (FQHSs) near filling factors ν = 3/4 and 5/4. The data reveal that these are spin-polarization transitions of interacting two-flux composite Fermions, which form their own FQHSs at these fillings. The fact that the reentrant integer quantum Hall effect near ν = 4/5 always develops following the transition to full spin polarization of the ν = 4/5 FQHS strongly links the reentrant phase to a pinned ferromagnetic Wigner crystal of two-flux composite Fermions.Fractional quantum Hall states (FQHSs) are among the most fundamental hallmarks of ultra-clean interacting two-dimensional electron systems (2DESs) at a large perpendicular magnetic field (B ⊥ ) [1]. These incompressible quantum liquid phases, signaled by the vanishing of the longitudinal resistance (R xx ) and the quantization of the Hall resistance (R xy ), can be explained by mapping the interacting electrons to a system of essentially noninteracting, 2p-flux composite Fermions ( 2p CFs), each formed by attaching 2p magnetic flux quanta to an electron (p is an integer). The 2p CFs have discrete energy levels, the so-called Λ-levels, and the FQHSs of electrons seen around Landau level (LL) filling factor ν = 1/2 (1/4) would correspond to the integer quantum Hall states of 2 CFs (. In state-of-the-art, highmobility 2DESs, FQHSs also develop around ν = 3/4, and are usually understood as the particle-hole counterparts of the FQHSs near ν = 1/4 through the relation. Alternatively, these states might also be the FQHSs of interacting 2 CFs at ν CF = ν/(1 − 2ν). For example, the ν = 4/5 state is the ν CF = −4/3 FQHS of 2p CFs, and has the same origin as the unconventional FQHS seen at ν = 4/11 (ν CF = 4/3) [5,6].Another hallmark of clean 2DESs is an insulating phase that terminates the series of FQHSs at low fillings, near ν = 1/5, [7,8]. This insulating phase is generally believed to be an electron Wigner crystal, pinned by the small but ubiquitous disorder potential [9]. Recently, an insulating phase was observed near ν = 4/5 in clean 2DESs [10,11]. This phase, which is signaled by a reentrant integer quantum Hall state (RIQHS) near ν = 1, was interpreted as the particle-hole symmetric state of the Wigner crystal seen at very small ν [10,11]. In this picture, the holes, unoccupied states in the lowest LL, have filling factor ν h ∼ 1/5 (= 1 − 4/5) and form a liquid phase when the short-range interaction is strong; see the left panel of Fig. 1(a). They turn into a solid phase when the thickness of the 2DES increases and the long-range interaction dominates (right panel of Fig. 1(a)). This interpretation is plausible, since the RIQHS only appears when the well-width (W ) is more than five times larger than the magnetic length. However, it does not predict or allow for any transitions of the ν = 4/5 FQHS, which is always seen just before the RIQHS de...