Enhancing the mechanical features of poly(vinyl) alcohol nanofibers with the addition of boron nitride

Abstract

Improvement of nano-sized products with boron additives with remarkable properties has become a popular trend for many different application areas. Here, we have reported an efficient poly(vinyl alcohol) (PVA) based composite nanofiber which was functionalized with the hexagonal boron nitride (h-BN) via electrospinning technique, for the first time as far as known, for body-armor and protective clothing applications. PVA-based composite nanofibers containing h-BN with a diameter of approximately 326 nm have shown significant mechanical features compared to pure PVA nanofibers with a diameter of about 223 nm. Mechanical features were investigated by nanoindentation and the results of nanoindentation demonstrated that the elastic modulus of PVA nanofibers increased by 77%, and hardness values of polymeric nanofibers reached ten times more, by the addition of h-BN. FTIR and XRD characterizations approved that there is no chemical change of h-BN when it was integrated into the PVA based composite nanofibers. We exceptionally believe that the achieved results offer a potential lightness and cost-effective strategy for body armor and protective clothing applications in contrast to boron carbide-based body armor products, which have main problems such as weightiness and high-priced.

Carvacrol-loaded polyvinyl alcohol/montmorillonite clay nanocomposite (PVA/MONT/Carva) as an antimicrobial agent for wound dressing

“…Both chemicals displayed the -OH stretch at wavenumbers of 3352.01 and 3435 cm -1 , respectively. Similar peaks of -OH stretch, C-H stretch and C-O stretch from PVA was reported by Alhosseini et al (2012) and Gergeroğlu et al (2020). According to Alhosseini et al (2012), the broad and sharp band in a range of 3550 and 3200 cm −1 is linked to -OH stretch, which associated with water molecules present in the tested sample.…”

“…The functional group for C-O acetyl group at wavenumber 1093 cm -1 has confirmed the presence of PVA in the developed film. This group is the remaining acetate group in PVA produced during the saponification (Gergeroğlu et al, 2020).…”