Enhancing Effect of Fullerene Guest and Counterion on the Structural Stability and Electrical Conductivity of Octahedral Metallo‐Supramolecular Cages
Shuai Lu,
Ziang Zhang,
Yiying Zhu
et al.
Abstract:Metallo‐supramolecular cages have garnered tremendous attention for their diverse yet molecular‐level precision structures. However, physical properties of these supramolecular ensembles, which are of potential significance in molecular electronics, remain largely unexplored. We herein constructed a series of octahedral metallo‐cages and cage‐fullerene complexes with notably enhanced structural stability. As such, we could systematically evaluate the electrical conductivity of these ensembles at both single‐mo… Show more
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