Carbon nanotube fibers
(CNFs) are a promising material for use as lightweight, high-strength,
electrically conducting tool cathodes in wire electrochemical micromachining
(WECMM) in which a high-performance tool cathode is crucial for optimal
processing performance. However, the outstanding advantages of pristine
CNFs, such as fiber strength, electrical conductivity, and hydrophilic
surface, have so far remained underutilized as tool cathodes in WECMM.
Herein, electrochemical modification using a dynamic liquid membrane
is proposed as an effective online method for functionalizing CNFs
prior to WECMM. The proposed method not only improves the assembly
accuracy and efficiency but also avoids unnecessary damage to the
modified CNF during installation. The introduced functional groups
(−OH and −COOH) effectively improved the electrical
conductivity and hydrophilicity of CNFs. The influences of H2O2 concentration, applied voltage, and anodization time
on the surface modification process were examined experimentally.
The use of a pulsed voltage was further proposed to prevent the loss
of fiber strength due to over-anodization. Finally, the use of modified
CNF electrodes with good surface morphology, strength, and conductivity
in WECMM was demonstrated to afford superior machining stability,
efficiency, and accuracy as well as improved surface quality compared
with the conventional tool cathodes.